Evidence map›Paper›PMID 37819708›Full record

ArticleJournal of the American Chemical Society2023

Interfacial Bonding between a Crystalline Metal-Organic Framework and an Inorganic Glass.

Celia Castillo-Blas, Ashleigh M Chester, Ronan P Cosquer, Adam F Sapnik, Lucia Corti, Roman Sajzew, Bruno Poletto-Rodrigues, Georgina P Robertson, Daniel J M Irving, Lauren N McHugh and 4 more

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

14 authors.

Celia Castillo-BlasDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, U.K.
Ashleigh M ChesterDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, U.K.
Ronan P CosquerDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, U.K.
Adam F SapnikDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, U.K.ORCID 0000-0001-6200-4208
Lucia CortiDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, U.K.ORCID 0000-0001-6493-8135
Roman SajzewOtto Schott Institute of Materials Research, University of Jena, Fraunhoferstrasse 6, 07743 Jena, Germany.
Bruno Poletto-RodriguesOtto Schott Institute of Materials Research, University of Jena, Fraunhoferstrasse 6, 07743 Jena, Germany.ORCID 0000-0003-1785-8946
Georgina P RobertsonDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, U.K.
Daniel J M IrvingDiamond Light Source Ltd., Diamond House, Harwell Campus, Didcot, Oxfordshire OX11 0QX, U.K.
Lauren N McHughDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, U.K.
Lothar WondraczekOtto Schott Institute of Materials Research, University of Jena, Fraunhoferstrasse 6, 07743 Jena, Germany.ORCID 0000-0002-0747-3076
Frédéric BlancDepartment of Chemistry, University of Liverpool, Crown Street, Liverpool L69 7ZD, U.K.ORCID 0000-0001-9171-1454
David A KeenISIS Facility, Rutherford Appleton Laboratory, Harwell Campus, Didcot, Oxfordshire OX11 0QX, U.K.ORCID 0000-0003-0376-2767
Thomas D BennettDepartment of Materials Science and Metallurgy, University of Cambridge, Cambridge CB3 0FS, U.K.ORCID 0000-0003-3717-3119

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The interface within a composite is critically important for the chemical and physical properties of these materials. However, experimental structural studies of the interfacial regions within metal-organic framework (MOF) composites are extremely challenging. Here, we provide the first example of a new MOF composite family, i.e., using an inorganic glass matrix host in place of the commonly used organic polymers. Crucially, we also decipher atom-atom interactions at the interface. In particular, we dispersed a zeolitic imidazolate framework (ZIF-8) within a phosphate glass matrix and identified interactions at the interface using several different analysis methods of pair distribution function and multinuclear multidimensional magic angle spinning nuclear magnetic resonance spectroscopy. These demonstrated glass-ZIF atom-atom correlations. Additionally, carbon dioxide uptake and stability tests were also performed to check the increment of the surface area and the stability and durability of the material in different media. This opens up possibilities for creating new composites that include the intrinsic chemical properties of the constituent MOFs and inorganic glasses.

Identifiers

PMID37819708
PMCPMC10603780

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.