Evidence map›Paper›PMID 37814032›Full record

ReviewNature reviews. Chemistry2023

Advances in heterogeneous single-cluster catalysis.

Xinzhe Li, Sharon Mitchell, Yiyun Fang, Jun Li, Javier Perez-Ramirez, Jiong Lu

Abstract readReview
PubMed Publisher
In one paragraph

Review in Nature reviews. Chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 54 papers.

0numbers the graph read from it
0cells of the map it votes in
54citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

54 citing papers in PubMed.

  1. Article
  2. Review
  3. Article
  4. Review
  5. Support-Mediated Reversible Redox Dynamics of Pt and Au on CeOSmall (Weinheim an der Bergstrasse, Germany) · 2026
    Article
  6. Article
  7. Structural Evolution, Electronic, Bonding, and Magnetic Properties of TiChemphyschem : a European journal of chemical physics and physical chemistry · 2026
    Article
  8. BSrPrecision chemistry · 2026
    Article
  9. Article
  10. Review
  11. Article
  12. Article
  13. Article
  14. Article
  15. Atomically Precise Clusterzymes: A Programmable Optoelectronic Platform for Neuroscience.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026
    Review
  16. Review
  17. Rational design of CiScience · 2026
    Review
  18. Asymmetric PtNature communications · 2026
    Article
  19. Article
  20. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors.

Xinzhe Li *Department of Environmental Science and Engineering, School of Energy and Power Engineering, Xi'an Jiaotong University, Xi'an, Shaanxi, China.ORCID http://orcid.org/0000-0001-6636-0496
Sharon Mitchell *Institute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Zurich, Switzerland.ORCID http://orcid.org/0000-0002-3933-2913
Yiyun FangDepartment of Chemistry, National University of Singapore, Singapore, Singapore.ORCID http://orcid.org/0000-0002-0461-2544
Jun LiDepartment of Chemistry and Engineering Research Center of Advanced Rare-Earth Materials of Ministry of Education, Tsinghua University, Beijing, China. junli@mail.tsinghua.edu.cn.ORCID http://orcid.org/0000-0002-8456-3980
Javier Perez-RamirezInstitute for Chemical and Bioengineering, Department of Chemistry and Applied Biosciences, ETH Zurich, Zurich, Switzerland. jpr@chem.ethz.ch.ORCID http://orcid.org/0000-0002-5805-7355
Jiong LuDepartment of Chemistry, National University of Singapore, Singapore, Singapore. chmluj@nus.edu.sg.ORCID http://orcid.org/0000-0002-3690-8235

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Heterogeneous single-cluster catalysts (SCCs) comprising atomically precise and isolated metal clusters stabilized on appropriately chosen supports offer exciting prospects for enabling novel chemical reactions owing to their broad structural diversity with unparalled opportunities for engineering their properties. Although the pioneering work revealed intriguing performance trends of size-selected metal clusters deposited on supports, synthetic and analytical challenges hindered a thorough understanding of surface chemistry under realistic conditions. This Review underscores the importance of considering the cluster environment in SCCs, encompassing the development of robust metal-support interactions, precise control over the ligand sphere, the influence of reaction media and dynamic behaviour, to uncover new reactivities. Through examples, we illustrate the criticality of tailoring the entire catalytic ensemble in SCCs to achieve stable and selective performance with practically relevant metal coverages. This expansion in application scope transcends from model reactions to complex and technically relevant reactions. Furthermore, we provide a perspective on the opportunities and future directions for SCC design within this rapidly evolving field.

Identifiers

PMID37814032

What OpenQuestion holds

Textmetadata
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.