ArticleJournal of the American Chemical Society2023
Implementing Mesoporosity in Zeolitic Imidazolate Frameworks through Clip-Off Chemistry in Heterometallic Iron-Zinc ZIF-8.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
What it found
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Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
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Who cites it
5 citing papers in PubMed.
- Supramolecular Chemistry in Metal-Organic Framework Materials.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Impact of N-heterocyclic amine modulators on the structure and thermal conversion of a zeolitic imidazole framework.Journal of materials chemistry. A · 2025Article
- Efficient visible-light-driven photocatalytic detoxification of a sulfur mustard simulant in air using rose bengal-functionalized MOFs.RSC advances · 2025Article
- Stable Compressible Liquids Made of Hierarchical MOF Nanocrystals.ACS applied materials & interfaces · 2025Article
- Hierarchically Micro- and Mesoporous Zeolitic Imidazolate Frameworks Through Selective Ligand Removal.Small (Weinheim an der Bergstrasse, Germany) · 2024Article
Corrections and comments
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Authors and funding
10 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Bond breaking has emerged as a new tool to postsynthetically modify the pore structure in metal-organic frameworks since it allows us to obtain pore environments in structures that are inaccessible by other techniques. Here, we extend the concept of clip-off chemistry to archetypical ZIF-8, taking advantage of the different stabilities of the bonds between imidazolate and Zn and Fe metal atoms in heterometallic Fe-Zn-ZIF-8. We demonstrate that Fe centers can be removed selectively without affecting the backbone of the structure that is supported by the Zn atoms. This allows us to create mesopores within the highly stable ZIF-8 structure. The strategy presented, combined with control of the amount of iron centers incorporated into the structure, permits porosity engineering of ZIF materials and opens a new avenue for designing novel hierarchical porous frameworks.
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Registered trials
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