Evidence map›Paper›PMID 37805942›Full record

ArticleACS nano2023

Directing Intrinsic Chirality in Gold Nanoclusters: Preferential Formation of Stable Enantiopure Clusters in High Yield and Experimentally Unveiling the "Super" Chirality of Au

Vera Truttmann, Adea Loxha, Rareş Banu, Ernst Pittenauer, Sami Malola, María Francisca Matus, Yuchen Wang, Elizabeth A Ploetz, Günther Rupprechter, Thomas Bürgi and 3 more

Abstract read
In one paragraph

Article in ACS nano, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.

0numbers the graph read from it
0cells of the map it votes in
10citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

10 citing papers in PubMed.

  1. Article
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  10. Two-Photon and Three-Photon Circular Dichroism of AuJournal of the American Chemical Society · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Vera TruttmannInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Adea LoxhaInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Rareş BanuInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.
Ernst PittenauerInstitute of Chemical Technologies and Analytics, TU Wien, Getreidemarkt 9/E164, 1060 Vienna, Austria.ORCID 0000-0002-8409-802X
Sami MalolaDepartments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.
María Francisca MatusDepartments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.ORCID 0000-0002-4816-531X
Yuchen WangDepartment of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States of America.ORCID 0000-0002-4947-4907
Elizabeth A PloetzDepartment of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States of America.ORCID 0000-0001-9812-0198
Günther RupprechterInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.ORCID 0000-0002-8040-1677
Thomas BürgiDepartment of Physical Chemistry, University of Geneva, 30 Quai Ernest-Ansermet, 1211 Geneva 4, Switzerland.ORCID 0000-0003-0906-082X
Hannu HäkkinenDepartments of Physics and Chemistry, Nanoscience Center, University of Jyväskylä, FI-40014 Jyväskylä, Finland.ORCID 0000-0002-8558-5436
Christine AikensDepartment of Chemistry, Kansas State University, Manhattan, Kansas 66506, United States of America.ORCID 0000-0002-0854-7997
Noelia BarrabésInstitute of Materials Chemistry, TU Wien, Getreidemarkt 9/E165, 1060 Vienna, Austria.ORCID 0000-0002-6018-3115

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Chiral gold nanoclusters offer significant potential for exploring chirality at a fundamental level and for exploiting their applications in sensing and catalysis. However, their widespread use is impeded by low yields in synthesis, tedious separation procedures of their enantiomeric forms, and limited thermal stability. In this study, we investigated the direct synthesis of enantiopure chiral nanoclusters using the chiral ligand 2-MeBuSH in the fabrication of Au

Indexed as

chiralitydensity functional theorygoldintrinsically chiralligandmetal nanoclustersyield

Identifiers

PMID37805942
PMCPMC10604085

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.