ArticleChemical science2023
-SR removal or -R removal? A mechanistic revisit on the puzzle of ligand etching of Au
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
2 citing papers in PubMed.
- Rate and mechanism of thiolate deligation in AuChemical science · 2026Article
- Atomically Precise Cu Nanoclusters: Recent Advances, Challenges, and Perspectives in Synthesis and Catalytic Applications.Nano-micro letters · 2024Review
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Authors and funding
8 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Accurate identification of active sites is highly desirable for elucidation of the reaction mechanism and development of efficient catalysts. Despite the promising catalytic performance of thiolated metal nanoclusters (NCs), their actual catalytic sites remain elusive. Traditional first-principles calculations and experimental observations suggested dealkylated S and dethiolated metal, respectively, to be the active centers. However, the real kinetic origin of thiolate etching during the electrocatalysis of NCs is still puzzling. Herein, we conducted advanced first-principles calculations and electrochemical/spectroscopic experiments to unravel the electrochemical etching kinetics of thiolate ligands in prototype Au
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Registered trials
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