ArticleJournal of the American Chemical Society2023
Photocatalytic Generation of Divalent Lanthanide Reducing Agents.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 15 papers.
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Who cites it
15 citing papers in PubMed, 41 citations in OpenAlex.
- Solution-Phase Electrochemical Characterization of Acyclic Complexes of Divalent Europium.Inorganic chemistry · 2026Article
- Photochemical strategies in divalent samarium catalysis.Beilstein journal of organic chemistry · 2026Review
- A Luminescence-Based Screening Platform for Lanthanide-Binding Peptides and Proteins.ACS chemical biology · 2025Article
- Electronic energy levels and optical spectra of trivalent lanthanide ions in water - Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), Gd(III), Tb(III), Dy(III), Ho(III), Er(III), Tm(III), and Yb(III).Nature communications · 2025Article
- Contemporary Strategies in SmIAngewandte Chemie (International ed. in English) · 2025Review
- Rapid Methylation of Aryl Bromides Using Air-Stable DABCO-Bis(Trimethylaluminum) via Nickel Metallaphotoredox Catalysis.Angewandte Chemie (International ed. in English) · 2025Article
- Cooperative Ammonia Formation Catalyzed by Molybdenum and Samarium Complexes.Angewandte Chemie (International ed. in English) · 2025Article
- Reduction of Hexaazatrinaphthylenes by Masked Divalent Lanthanide Dinitrogen Reagents.Inorganic chemistry · 2025Article
- Slow Magnetic Relaxation in a Rare, Neutral, Formally Divalent Terbium Bis(amide) Complex.Inorganic chemistry · 2025Article
- Catalytic Reductive Homocoupling of Benzyl Chlorides Enabled by Zirconocene and Photoredox Catalysis.Precision chemistry · 2025Article
- Divalent Intermediates in Lanthanide-Based Photocatalysts: Spectroscopic Characterization and Reactivity.Inorganic chemistry · 2025Article
- Photocatalyst for Visible-Light-Driven Sm(II)-Mediated Reductions.Organic letters · 2024Article
- Photodriven Sm(III)-to-Sm(II) Reduction for Catalytic Applications.Journal of the American Chemical Society · 2024Article
- Alkyl Cyclopropyl Ketones in Catalytic Formal [3 + 2] Cycloadditions: The Role of SmIJournal of the American Chemical Society · 2024Article
- Rare Earths-The Answer to Everything.Molecules (Basel, Switzerland) · 2024Review
Corrections and comments
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Authors and funding
5 authors at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Divalent lanthanide (Ln) compounds are excellent reducing agents with unique reactivity profiles. These reagents are typically used in superstoichiometric amounts, often in combination with harmful additives. Reactions catalytic in Ln(II) reagents that retain the reactivity and selectivity of the stoichiometric transformations are currently lacking due to the absence of effective and selective methods to form reactive Ln(II) species from stable precursors. Here, active Ln(II) is generated from a Ln(III) precursor through reduction by a photoexcited coumarin or carbostyril chromophore, which, in turn, is regenerated by a sacrificial reductant. The reductant can be metallic (Zn) or organic (amines) and can be used in strictly stoichiometric amounts. A broad range of reactions, including C-halogen, C═C, C═X (X = O, N), P═O, and N═N reductions, as well as C-C, C-X (X = N, S, P), and N-N couplings were readily carried out in yields and selectivities comparable to or better than those afforded by the analogous stoichiometric transformations. The reaction outcomes could be altered by changing the ligand or the lanthanide or through the addition of environmentally benign additives (e.g., water). EPR spectroscopy supported the formation of both Ln(II) and oxidized chromophore intermediates. Taken together, these results establish photochemical Ln(II) generation as a powerful strategy for rendering Ln(II)-mediated reactions catalytic.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.