Evidence map›Paper›PMID 37792665›Full record

ArticleThe Journal of organic chemistry2023

Visible Light-Promoted β-Functionalization of Carbonyl Compounds in the Presence of Organic Dyes.

Luigi Dolcini, Tommaso Gandini, Riccardo Castiglioni, Alberto Bossi, Marta Penconi, Alberto Dal Corso, Cesare Gennari, Luca Pignataro

Open access · hybridAbstract read
In one paragraph

Article in The Journal of organic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.7field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 5 citations in OpenAlex.

  1. Bifunctional Photocatalysts: Exploiting Proximity for Enhanced Reaction Performance.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 1 institution in 1 country.

Luigi DolciniDipartimento di Chimica, Università degli Studi di Milano, via C. Golgi 19, Milano 20133, Italy.ORCID 0000-0001-9455-9785
Tommaso GandiniDipartimento di Chimica, Università degli Studi di Milano, via C. Golgi 19, Milano 20133, Italy.ORCID 0000-0002-3682-914X
Riccardo CastiglioniDipartimento di Chimica, Università degli Studi di Milano, via C. Golgi 19, Milano 20133, Italy.
Alberto BossiIstituto di Scienze e Tecnologie Chimiche "Giulio Natta" (SCITEC) del Consiglio Nazionale delle Ricerche (CNR), via Fantoli 16/15; SmartMatLab Center, via C. Golgi 19, Milano 20138, Italy.ORCID 0000-0001-9252-6218
Marta PenconiIstituto di Scienze e Tecnologie Chimiche "Giulio Natta" (SCITEC) del Consiglio Nazionale delle Ricerche (CNR), via Fantoli 16/15; SmartMatLab Center, via C. Golgi 19, Milano 20138, Italy.ORCID 0000-0001-7459-7354
Alberto Dal CorsoDipartimento di Chimica, Università degli Studi di Milano, via C. Golgi 19, Milano 20133, Italy.ORCID 0000-0003-4437-8307
Cesare GennariDipartimento di Chimica, Università degli Studi di Milano, via C. Golgi 19, Milano 20133, Italy.ORCID 0000-0002-7635-4900
Luca PignataroDipartimento di Chimica, Università degli Studi di Milano, via C. Golgi 19, Milano 20133, Italy.ORCID 0000-0002-7200-9720
University of Milan · IT

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Herein, we investigate the use of organic photocatalysts in the visible light-promoted β-functionalization of carbonyl compounds. In particular, we studied the addition of aliphatic aldehydes to α,β-unsaturated compounds (β-Michael addition), and the reaction of cyclic ketones with either ketones (β-aldol condensation) or imines (β-Mannich reaction). Among the dyes tested, donor-acceptor cyanoarenes gave the best results, promoting the transformations of interest in moderate to good yields. The reaction scope was investigated on substrates with different steric and electronic properties. Fluorescence quenching analysis (Stern-Volmer experiments) led us to propose for these reactions a reductive quenching mechanism involving a transient 5πe

Identifiers

PMID37792665
PMCPMC10594657
OpenAlexW4387331504

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.