Evidence map›Paper›PMID 37790600›Full record

ArticleSynthesis2023

Reactions of Benzylboronate Nucleophiles.

Timothy J Barker, Andrew Bogatkevich, Dallas W Crowder, Sophia G Gierszal, Jacob C Hayes, Michael R Hollerbach, Richard W Russell

Abstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Synthesis, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Timothy J BarkerCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.
Andrew BogatkevichCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.
Dallas W CrowderCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.
Sophia G GierszalCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.
Jacob C HayesCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.
Michael R HollerbachCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.
Richard W RussellCollege of Charleston, Department of Chemistry and Biochemistry, 66 George St., Charleston, SC.

Funding

South Carolina IDeA Networks of Biomedical Research (SC INBRE V)P20GM103499 · NIGMS · UNIVERSITY OF SOUTH CAROLINA AT COLUMBIA · PI EDIE C GOLDSMITH · 2012 to 2026
$61.0M
Supplement for South Carolina BRIN - 1P20 RR16461P20RR016461 · NCRR · UNIVERSITY OF SOUTH CAROLINA AT COLUMBIA · PI DEAVOR, JAMES · 2001 to 2011
$32.3M
NCRR NIH HHS P20 RR016461NIGMS NIH HHS P20 GM103499
6 · The paper itself

Abstract

This short review summarizes our laboratory's development of benzylboronic esters as nucleophiles. Activation of the benzylboronic ester is achieved by irreversible coordination of an alkyllithium Lewis base to form a nucleophilic benzylboronate. This boronate was found to react with aldehydes, imines, ketones and alkyl bromides. A copper catalyst was employed in reactions of the boronate with epoxides and aziridines.

Identifiers

PMID37790600
PMCPMC10545366

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.