ReviewACS physical chemistry Au2023
Theoretical Insights into the Dynamics of Gas-Phase Bimolecular Reactions with Submerged Barriers.
Review in ACS physical chemistry Au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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Who cites it
3 citing papers in PubMed.
- Probing resonances in the double-well entry valley of the Cl + NHNature communications · 2026Article
- Conditions for enhancement of gas phase chemical reactions inside a dark microwave cavity.Communications chemistry · 2024Article
- Probing the activated complex of the F + NHNature communications · 2024Article
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Authors and funding
2 authors.
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Abstract
Much attention has been paid to the dynamics of both activated gas-phase bimolecular reactions, which feature monotonically increasing integral cross sections and Arrhenius kinetics, and their barrierless capture counterparts, which manifest monotonically decreasing integral cross sections and negative temperature dependence of the rate coefficients. In this Perspective, we focus on the dynamics of gas-phase bimolecular reactions with submerged barriers, which often involve radicals or ions and are prevalent in combustion, atmospheric chemistry, astrochemistry, and plasma chemistry. The temperature dependence of the rate coefficients for such reactions is often non-Arrhenius and complex, and the corresponding dynamics may also be quite different from those with significant barriers or those completely dominated by capture. Recent experimental and theoretical studies of such reactions, particularly at relatively low temperatures or collision energies, have revealed interesting dynamical behaviors, which are discussed here. The new knowledge enriches our understanding of the dynamics of these unusual reactions.
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