ReviewChemistry of materials : a publication of the American Chemical Society2023
Zintl Phases: From Curiosities to Impactful Materials.
Review in Chemistry of materials : a publication of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
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Who cites it
16 citing papers in PubMed, 81 citations in OpenAlex.
- Pressure-induced modulation of structural, mechanical, electronic, optical, and thermodynamic properties of KZnRSC advances · 2026Article
- Vibrational spectroscopy, structure and bonding in the family of aluminium-doped niobium clusters, AlNbPhysical chemistry chemical physics : PCCP · 2026Article
- SmInorganic chemistry · 2026Article
- Leveraging Polymorphism in YbCuBi to Map Transport and Elastic Properties.Chemistry of materials : a publication of the American Chemical Society · 2026Article
- Isolation of Potassium Bis(amido)diazadipnictogenide Salts.Organometallics · 2026Article
- The Zintl-Klemm Concept in the Amorphous State: A Case Study of Na-P Battery Anodes.Angewandte Chemie (International ed. in English) · 2026Article
- Map of the Zintl AMChemistry of materials : a publication of the American Chemical Society · 2025Article
- Synthesis and Characterization of Zintl-Phase BaCdACS nano · 2025Article
- Interplay of Crystal Structure and Magnetic Properties of the EuInorganic chemistry · 2025Article
- Zintl Clusters as a Platform for Lewis Acid Catalysis.Inorganic chemistry · 2024Article
- Advancing Heteroanionicity in Zintl Phases: Crystal Structures, Thermoelectric and Magnetic Properties of Two Quaternary Semiconducting Arsenide Oxides, EuInorganic chemistry · 2024Article
- Zintl Phase versus Covalent Metal: Chemical Bonding in Silicon Dumbbells of CaInorganic chemistry · 2024Article
- Liquid Ammonia: More than an Innocent Solvent for Zintl Anions.Inorganic chemistry · 2024Article
- An Organometallic Erbium Bismuth Cluster Complex Comprising a BiInorganic chemistry · 2024Article
- Reactivity of Tetrel-Functionalized Heptaphosphane Clusters toward Azides.Inorganic chemistry · 2024Article
- Zintl Ions and Phases Promote the Catalytic Hydrophosphination of Alkynes, Alkenes, and Imines.Organometallics · 2024Article
Corrections and comments
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Authors and funding
1 author at 1 institution in 1 country.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The synthesis of new compounds and crystal structures remains an important research endeavor in pursuing technologically relevant materials. The Zintl concept is a guidepost for the design of new functional solid-state compounds. Zintl phases are named in recognition of Eduard Zintl, a German chemist who first studied a subgroup of intermetallics prepared with electropositive metals combined with main-group metalloids from groups 13-15 in the 1930s. Unlike intermetallic compounds, where metallic bonding is the norm, Zintl phases exhibit a combination of ionic and covalent bonding and are typically semiconductors. Zintl phases provide a palette for iso- and aliovalent substitutions that can each contribute uniquely to the properties. Zintl electron-counting rules can be employed to interrogate a structure type and develop a foundation of structure-property relationships. Employing substitutional chemistry allows for the rational design of new Zintl compounds with technological properties, such as magnetoelectronics, thermoelectricity, and other energy storage and conversion capabilities. Discovering new structure types and compositions through this approach is also possible. The background on the strength and innovation of the Zintl concept and a few highlights of Zintl phases with promising thermoelectric properties in the context of structural and electronic design will be provided.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.