ReviewCommunications chemistry2023
Recent advances in enantioselective ring-opening polymerization and copolymerization.
Review in Communications chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
13 citing papers in PubMed.
- New Biobased Polyester Polyols With Tunable TChemSusChem · 2026Article
- Stereoselective Ring-Opening Polymerization of Racemic Dithiolactones Assisted by Non-Classical C─H⋯X Interactions.Angewandte Chemie (International ed. in English) · 2026Article
- Rapid and Stereoselective Ring-Opening Polymerization of rac-Lactide Enabled by a Chiral Cyclopropenimine-Thiourea Catalyst.Angewandte Chemie (International ed. in English) · 2026Article
- Simplifying the problem: metal salts can be active and controlled catalysts in polyester synthesis.Chemical science · 2026Review
- Review
- Spirosalen-scandium catalysts enable the epimerization-tolerant closed-loop circularity of poly(l-lactic acid).National science review · 2025Article
- Stereoconvergent Chain-Growth Polymerization.ACS central science · 2025Article
- Polyester Adhesives via One-Pot, One-Step Copolymerization of Cyclic Anhydride, Epoxide, and Lactide.Polymers · 2024Article
- Fully recyclable and tough thermoplastic elastomers from simple bio-sourced δ-valerolactones.Nature communications · 2024Article
- Organomediated polymerization.Communications chemistry · 2024Article
- Ring Opening Polymerization of Six- and Eight-Membered Racemic Cyclic Esters for Biodegradable Materials.International journal of molecular sciences · 2024Review
- Exploiting Multimetallic Cooperativity in the Ring-Opening Polymerization of Cyclic Esters and Ethers.ACS catalysis · 2024Review
- Mechanism of Alternating Poly(lactic-ACS catalysis · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Precisely controlling macromolecular stereochemistry and sequences is a powerful strategy for manipulating polymer properties. Controlled synthetic routes to prepare degradable polyester, polycarbonate, and polyether are of recent interest due to the need for sustainable materials as alternatives to petrochemical-based polyolefins. Enantioselective ring-opening polymerization and ring-opening copolymerization of racemic monomers offer access to stereoregular polymers, specifically enantiopure polymers that form stereocomplexes with improved physicochemical and mechanical properties. Here, we highlight the state-of-the-art of this polymerization chemistry that can produce microstructure-defined polymers. In particular, the structures and performances of various homogeneous enantioselective catalysts are presented. Trends and future challenges of such chemistry are discussed.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.