Evidence map›Paper›PMID 37772828›Full record

ArticleAngewandte Chemie (International ed. in English)2023

Experimental and Computational Studies on Cobalt(I)-Catalyzed Regioselective Allylic Alkylation Reactions.

Philip Andreetta, Robert T Martin, Charafa Souilah, Ángel Rentería-Gómez, Zhihui Song, Yas Khorramshahi Bayat, Sergei Ivlev, Osvaldo Gutierrez, Alicia Casitas

Abstract read
In one paragraph

Article in Angewandte Chemie (International ed. in English), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

9 authors.

Philip AndreettaFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35043, Marburg, Germany.
Robert T MartinDepartment of Chemistry and Biochemistry, University of Maryland, College Park. 8051 Regents Dr, College Park, Maryland, 20742, USA.
Charafa SouilahFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35043, Marburg, Germany.
Ángel Rentería-GómezDepartment of Chemistry, Texas A&M University, College Station, Texas, 77843, USA.
Zhihui SongDepartment of Chemistry and Biochemistry, University of Maryland, College Park. 8051 Regents Dr, College Park, Maryland, 20742, USA.
Yas Khorramshahi BayatFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35043, Marburg, Germany.
Sergei IvlevFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35043, Marburg, Germany.
Osvaldo GutierrezDepartment of Chemistry, Texas A&M University, College Station, Texas, 77843, USA.ORCID https://orcid.org/0000-0001-8151-7519
Alicia CasitasFachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Straße 4, 35043, Marburg, Germany.ORCID https://orcid.org/0000-0001-6989-1751

Funding

New Directions in Sustainable Open-Shell Radical C-C Bond Formations Enabled by Merging Modern Computational and Experimental MethodsR35GM137797 · NIGMS · UNIV OF MARYLAND, COLLEGE PARK · PI Osvaldo Gutierrez · 2020 to 2026
$2.7M
NIGMS NIH HHS R35 GM137797
6 · The paper itself

Abstract

Here, we report the development of cobalt(I)-catalyzed regioselective allylic alkylation reactions of tertiary allyl carbonates with 1,3-dicarbonyl compounds. A family of well-defined tetrahedral cobalt(I) complexes bearing commercially available bidentate bis(phosphine) ligands [(P,P)Co(PPh

Indexed as

Allylic Alkylation ReactionCobalt CatalysisCoordination Cobalt(I) ComplexesReaction MechanismTheoretical Calculations

Identifiers

PMID37772828
PMCPMC10843511

What OpenQuestion holds

Textmetadata
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Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.