ArticleNature chemistry2024
A crystalline aluminium-carbon-based ambiphile capable of activation and catalytic transfer of ammonia in non-aqueous media.
Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 10 papers.
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Who cites it
10 citing papers in PubMed.
- Nucleophilic Gallyl Anions Enable Ga─Au Bimetallic Ammonia Activation.Angewandte Chemie (International ed. in English) · 2026Article
- Synthesis and Isolation of Bismuth Scorpionate Complexes: Toward Bond Activation via Bismuth-Ligand Cooperation.Chemistry (Weinheim an der Bergstrasse, Germany) · 2026Article
- Crystallinity-Gradient Etched Hollow Mesoporous Zinc Nanoparticle for Dual-Source HAdvanced healthcare materials · 2026Article
- Intramolecular Al/P Frustrated Lewis Pairs Based on an Indoline Backbone─Two Reaction Sites for Small Molecule Activation and Hydrodefluorination.Inorganic chemistry · 2026Article
- Double E─H Bond Activation of Ammonia and Water by Cyclic Gallaphosphene L(OCP)GaPGaL.Angewandte Chemie (International ed. in English) · 2026Article
- Recent Advances in Heterogeneous Frustrated Lewis Pair: Synthesis, Characterization, and Catalysis.Advanced materials (Deerfield Beach, Fla.) · 2025Review
- Metal-Ligand Cooperation in N-H Activation: Bridging Electron-Pushing Formalism and Energy Descriptors.Inorganic chemistry · 2025Article
- Regio- and chemoselective catalytic partial transfer hydrogenation of quinolines by dinuclear aluminum species.Nature communications · 2025Article
- Stepwise Acetylene Insertion and Ammonia Activation at a Digallene and Diindene.Angewandte Chemie (International ed. in English) · 2025Article
- Rethinking carbanion chemistry from donor substituents to weakly coordinating carbanions.Nature reviews. Chemistry · 2025Review
Corrections and comments
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Authors and funding
4 authors.
Funding
Abstract
Despite recent achievements in the field of frustrated Lewis pairs (FLPs) for small molecule activations, the reversible activation and catalytic transformations of N-H-activated ammonia remain a challenge. Here we report on a rare combination of an aluminium Lewis acid and a carbon Lewis base. A so-called hidden FLP consisting of a phosphorus ylide featuring an aluminium fragment in the ortho position of a phenyl ring scaffold is introduced. Although the formation of the Lewis acid/base adduct is observed in the solid state, which at first glance leads to formally quenched FLP reactivity, we show that the title compound readily reacts with non-aqueous ammonia thermoneutrally and splits the N-H bond reversibly at ambient temperature. In addition, NH
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37770550What OpenQuestion holds
Registered trials
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