ArticleNature communications2023
Iron phosphide nanocrystals as an air-stable heterogeneous catalyst for liquid-phase nitrile hydrogenation.
Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed.
- Hydrogen-Tolerant CuO/TiOAngewandte Chemie (International ed. in English) · 2026Article
- Bio-Inspired Hierarchical Nanoreactor With Hetero-Coordinated Fe-P-Co Bridges for Whole-Pathway-Regulated Electrocatalytic Oxygen Reduction.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Selective Hydrogenation of Heteroarenes Using Supported Ruthenium Phosphide Nanoparticle Catalysts.Journal of the American Chemical Society · 2026Article
- Competitive Adsorption and Modulated Product Binding Using Pyridines on Cobalt Phosphide Enhance Hydrogenation Catalysis.Journal of the American Chemical Society · 2025Article
- Dopant-Induced Hexagonal to Orthorhombic Phase Transition in FeChemistry of materials : a publication of the American Chemical Society · 2025Article
- Triacylphosphines as a Novel Class of Phosphorus Sources for the Synthesis of Transition Metal Phosphide Nanoparticles.Small (Weinheim an der Bergstrasse, Germany) · 2025Article
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Authors and funding
9 authors.
Funding
Abstract
Iron-based heterogeneous catalysts are ideal metal catalysts owing to their abundance and low-toxicity. However, conventional iron nanoparticle catalysts exhibit extremely low activity in liquid-phase reactions and lack air stability. Previous attempts to encapsulate iron nanoparticles in shell materials toward air stability improvement were offset by the low activity of the iron nanoparticles. To overcome the trade-off between activity and stability in conventional iron nanoparticle catalysts, we developed air-stable iron phosphide nanocrystal catalysts. The iron phosphide nanocrystal exhibits high activity for liquid-phase nitrile hydrogenation, whereas the conventional iron nanoparticles demonstrate no activity. Furthermore, the air stability of the iron phosphide nanocrystal allows facile immobilization on appropriate supports, wherein TiO
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