ArticleScience (New York, N.Y.)2023
Handling fluorinated gases as solid reagents using metal-organic frameworks.
Article in Science (New York, N.Y.), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 16 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
16 citing papers in PubMed, 54 citations in OpenAlex.
- Electroreductive Radical Olefin Difunctionalization with Fluorinated Gases Enabled by Dosage Delivery from a Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- Photochemical Fluoroalkylations with Fluorinated Gases Facilitated by a Robust Metal-Organic Framework.Journal of the American Chemical Society · 2026Article
- Factors Impacting the Nuclear Magnetic Resonance Spectra of Electrolyte Adsorbed in Layered Metal-Organic Frameworks.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- High-concentration aqueous synthesis of salicylate-based metal-organic frameworks.Journal of materials chemistry. A · 2025Article
- Defluorinative Coupling of (NH)-Heteroarenes and Unactivated Vinyl Fluorides Enabled by Metal-Organic Frameworks.Journal of the American Chemical Society · 2025Article
- Dual-ligand strategy boosted electrochemiluminescence sensing based on Tb-MOF/AgMikrochimica acta · 2025Article
- Controlled Growth and Interconversion of Photoluminescent Metal-Organic Frameworks Under High-Concentration Conditions.Chemistry of materials : a publication of the American Chemical Society · 2025Article
- High-Entropy Metal-Organic Frameworks and Their Derivatives: Advances in Design, Synthesis, and Applications for Catalysis and Energy Storage.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Uniform single-crystal mesoporous metal-organic frameworks.Nature chemistry · 2025Article
- Molecular Mechanism Behind the Capture of Fluorinated Gases by Metal-Organic Frameworks.Nano-micro letters · 2025Review
- Alkali-Stable Metal-Organic Frameworks with Enhanced Electroconductivity for Black-Brown Electrochromic Energy Storage Smart Window.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2024Article
- Gas Delivery Relevant to Human Health using Porous Materials.Chemistry (Weinheim an der Bergstrasse, Germany) · 2024Review
- Transdermal Hydrogen Sulfide Delivery Enabled by Open-Metal-Site Metal-Organic Frameworks.Journal of the American Chemical Society · 2024Article
- C-H and C-F bond activation of fluorinated propenes at Rh: enabling cross-coupling reactions with outer-sphere C-C coupling.Chemical science · 2024Article
- Oxidative Stress in Health and Disease.Biomedicines · 2023Review
- Simplifying the Synthesis of Metal-Organic Frameworks.Accounts of materials research · 2023Article
Corrections and comments
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Authors and funding
8 authors at 3 institutions in 2 countries.
Funding
Abstract
Fluorine is an increasingly common substituent in pharmaceuticals and agrochemicals because it improves the bioavailability and metabolic stability of organic molecules. Fluorinated gases represent intuitive building blocks for the late-stage installation of fluorinated groups, but they are generally overlooked because they require the use of specialized equipment. We report a general strategy for handling fluorinated gases as benchtop-stable solid reagents using metal-organic frameworks (MOFs). Gas-MOF reagents are prepared on gram-scale and used to facilitate fluorovinylation and fluoroalkylation reactions. Encapsulation of gas-MOF reagents within wax enables stable storage on the benchtop and controlled release into solution upon sonication, which represents a safer alternative to handling the gas directly. Furthermore, our approach enables high-throughput reaction development with these gases.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.