ArticleScience (New York, N.Y.)2023
Diverse functional polyethylenes by catalytic amination.
Article in Science (New York, N.Y.), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 22 papers.
What it found
Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.
The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.
Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.
Who cites it
22 citing papers in PubMed.
- Boosting Natural Rubber Performance by Backbone Rigid Functionalization.Angewandte Chemie (International ed. in English) · 2026Article
- Electrostatic-confinement-induced regioselective C-H functionalization of polyolefins.Nature communications · 2026Article
- Chiral S(VI) platform unifies selective C-H amination of complex molecules and alkane feedstocks.Science (New York, N.Y.) · 2026Article
- Direct Polymer-on-Polymer Grafting of Polyolefins under Visible Light.Journal of the American Chemical Society · 2026Article
- Microstructure of amide-functionalized polyethylenes determined by NMR relaxometry.Chemical science · 2026Article
- Synergistic Effects of Electricity and Light for Efficient Iron-Catalyzed Recycling of Polystyrene Waste.Angewandte Chemie (International ed. in English) · 2026Article
- Incorporating Carbamate Groups into Polyolefin Elastomers for High Performance and Closed-Loop Recyclability.Journal of the American Chemical Society · 2026Article
- Selective, Oxygen-Tunable, and Metal-Free Functionalization of Polyethylene Through Dual-Mode Nitrosation and Carbonylation.Angewandte Chemie (International ed. in English) · 2026Article
- The impact of dynamic bonding associations on the rheology of amine containing polyolefins.Discover polymers · 2026Review
- Tuning High-Density Polyethylene Microstructure and Properties from Known Distributions of Dynamic Bonds.Journal of the American Chemical Society · 2025Article
- Functionalization of Polyolefins via Catalytic Nitrene Addition.Angewandte Chemie (International ed. in English) · 2025Article
- Chemically Recyclable and Tunable Polyolefin-Like Multiblock Copolymer Adhesives.Angewandte Chemie (International ed. in English) · 2025Article
- Interfacial chain-growth polymerization enables polypropylene-like and circular polythioglycolide.Science advances · 2025Article
- Post-functionalization of polyethers by photoinduced C-H amidation via polar-radical relay.Nature communications · 2025Article
- Catalytic Borylation of Poly(vinyl chloride) Produces Adhesive Materials.Journal of the American Chemical Society · 2025Article
- Electrochemical Commodity Polymer Up- and Re-Cycling: Toward Sustainable and Circular Plastic Treatment.Macromolecular rapid communications · 2025Review
- Development of a Continuous Extrusion Process for Alginate Biopolymer Films for Sustainable Applications.Polymers · 2025Article
- Functionalized Polypropylene Copolymers as Multisubstrate Hot-Melt Adhesives.ACS applied materials & interfaces · 2025Article
- A Short Review on Polyethylene-based Ionomers: Synthesis, Structure, and Applications.Chem & bio engineering · 2025Review
- General (hetero)polyaryl amine synthesis via multicomponent cycloaromatization of amines.Nature communications · 2025Article
Corrections and comments
PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.
Authors and funding
11 authors.
Funding
Abstract
Functional polyethylenes possess valuable bulk and surface properties, but the limits of current synthetic methods narrow the range of accessible materials and prevent many envisioned applications. Instead, these materials are often used in composite films that are challenging to recycle. We report a Cu-catalyzed amination of polyethylenes to form mono- and bifunctional materials containing a series of polar groups and substituents. Designed catalysts with hydrophobic moieties enable the amination of linear and branched polyethylenes without chain scission or cross-linking, leading to polyethylenes with otherwise inaccessible combinations of functional groups and architectures. The resulting materials possess tunable bulk and surface properties, including toughness, adhesion to metal, paintability, and water solubility, which could unlock applications for functional polyethylenes and reduce the need for complex composites.
Identifiers
What OpenQuestion holds
Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.