Evidence map›Paper›PMID 37767035›Full record

ArticleNanoscale advances2023

A nanoscale study of the structure and electrical response of Sepia eumelanin.

Dieudonné Niyonkuru, Anthony Camus, Manuel Reali, Zhaojing Gao, Daniel M Shadrack, Oleg Butyaev, Marko Surtchev, Clara Santato

Open access · goldAbstract read
In one paragraph

Article in Nanoscale advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
1.3field-weighted citation impact, top 21% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 9 citations in OpenAlex.

  1. Article
  2. From melanogenesis to melanin technologies.Communications chemistry · 2025
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 2 countries.

Dieudonné NiyonkuruDepartment of Engineering Physics, Polytechnique Montréal C.P. 6079, Succ. Centre-Ville Montréal QC H3C3A7 Canada clara.santato@polymtl.ca.ORCID https://orcid.org/0000-0002-0362-683X
Anthony CamusDepartment of Engineering Physics, Polytechnique Montréal C.P. 6079, Succ. Centre-Ville Montréal QC H3C3A7 Canada clara.santato@polymtl.ca.ORCID https://orcid.org/0000-0002-4405-388X
Manuel RealiDepartment of Engineering Physics, Polytechnique Montréal C.P. 6079, Succ. Centre-Ville Montréal QC H3C3A7 Canada clara.santato@polymtl.ca.
Zhaojing GaoDepartment of Engineering Physics, Polytechnique Montréal C.P. 6079, Succ. Centre-Ville Montréal QC H3C3A7 Canada clara.santato@polymtl.ca.
Daniel M ShadrackDepartment of Chemistry, St. John's University of Tanzania P.O. Box 47 Dodoma Tanzania.ORCID https://orcid.org/0000-0002-4436-1487
Oleg ButyaevNT-MTD Spectrum Instruments 5861 S Kyrene Rd#19 Tempe AZ 85283 USA.
Marko SurtchevNT-MTD Spectrum Instruments 5861 S Kyrene Rd#19 Tempe AZ 85283 USA.
Clara SantatoDepartment of Engineering Physics, Polytechnique Montréal C.P. 6079, Succ. Centre-Ville Montréal QC H3C3A7 Canada clara.santato@polymtl.ca.ORCID https://orcid.org/0000-0001-6731-0538
Polytechnique Montréal · CASt. John's University of Tanzania · TZ

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Eumelanin, the brown-black member of the melanin biopigment family, is a prototype material for sustainable (green) organic electronics. Sepia eumelanin (Sepia) is a type of biosourced eumelanin extracted from the ink sac of cuttlefish. Electron microscopy and scanning probe microscopy images of Sepia show distinguishable near spherical granules with diameters of about 150-200 nm. We have recently reported on predominant electronic transport in printed films of Sepia formulated inks including the (insulating) binder Polyvinyl-butyral (PVB). In that work, we proposed that inter-granular percolative transport, observed for micrometric interelectrode distances, is promoted by the confining action of the PVB binder on the Sepia granules. Considering that inter-granular transport implies intra-granular transport, in this work we proceeded to a nanoscale study of Sepia granules by High Resolution Atomic Force Microscopy (HR-AFM) and Conductive-AFM (c-AFM). We have observed protrusions on the surface of the Sepia granules, suggesting sub-granular structures compatible with the hierarchical development of Sepia, as proposed elsewhere. For films of Sepia formulated inks deposited on gold-coated substrates, c-AFM revealed, for the very first time, a nanoscale electrical response. Nanoscale studies provide the key to structure-property relationships in biosourced materials strategic for sustainable organic electronics.

Identifiers

PMID37767035
PMCPMC10521209
OpenAlexW4386369658

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.