Evidence map›Paper›PMID 37765579›Full record

ArticlePolymers2023

Aqueous Cationic Fluorinated Polyurethane for Application in Novel UV-Curable Cathodic Electrodeposition Coatings.

Junhua Chen, Zhihao Zeng, Can Liu, Xuan Wang, Shiting Li, Feihua Ye, Chunsheng Li, Xiaoxiao Guan

Open access · goldAbstract read
In one paragraph

Article in Polymers, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
0.8field-weighted citation impact, top 33% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed, 8 citations in OpenAlex.

  1. Article
  2. Article
  3. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

8 authors at 2 institutions in 1 country.

Junhua ChenSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.ORCID 0000-0001-6270-4255
Zhihao ZengSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.ORCID 0009-0001-4762-2267
Can LiuSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.
Xuan WangSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.
Shiting LiSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.
Feihua YeSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.ORCID 0009-0005-0956-0770
Chunsheng LiSchool of Environmental and Chemical Engineering, Zhaoqing University, Zhaoqing 526061, China.
Xiaoxiao GuanChina Electronic Product Reliability and Environmental Testing Research Institute, Guangzhou 511370, China.
Zhaoqing University · CNChina Electronic Product Reliability and Environmental Test Institute · CN

Funding

Guangdong Basic and Applied Basic Research Foundation 2020A1515111156Guangdong Province Enterprise Science and Technology Special Representative GDKTP2021023000Guangdong University Innovation Project 2021KQNCX106)Zhaoqing University Science Fund 202006
6 · The paper itself

Abstract

Aqueous polyurethane is an environmentally friendly, low-cost, high-performance resin with good abrasion resistance and strong adhesion. Cationic aqueous polyurethane is limited in cathodic electrophoretic coatings due to its complicated preparation process and its poor stability and single performance after emulsification and dispersion. The introduction of perfluoropolyether alcohol (PFPE-OH) and light curing technology can effectively improve the stability of aqueous polyurethane emulsions, and thus enhance the functionality of coating films. In this paper, a new UV-curable fluorinated polyurethane-based cathodic electrophoretic coating was prepared using cationic polyurethane as a precursor, introducing PFPE-OH capping, and grafting hydroxyethyl methacrylate (HEMA). The results showed that the presence of perfluoropolyether alcohol in the structure affected the variation of the moisture content of the paint film after flash evaporation. Based on the emulsion particle size and morphology tests, it can be assumed that the fluorinated cationic polyurethane emulsion is a core-shell structure with hydrophobic ends encapsulated in the polymer and hydrophilic ends on the outer surface. After abrasion testing and baking, the fluorine atoms of the coating were found to increase from 8.89% to 27.34%. The static contact angle of the coating to water was 104.6 ± 3°, and the water droplets rolled off without traces, indicating that the coating is hydrophobic. The coating has excellent thermal stability and tensile properties. The coating also passed the tests of impact resistance, flexibility, adhesion, and resistance to chemical corrosion in extreme environments. This study provides a new idea for the construction of a new and efficient cathodic electrophoretic coating system, and also provides more areas for the promotion of cationic polyurethane to practical applications.

Indexed as

cathodic electrodeposition coatingscationic polyurethaneperfluoropolyether alcoholUV-curable

Identifiers

PMID37765579
PMCPMC10535655
OpenAlexW4386607618

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.