ArticleNanomaterials (Basel, Switzerland)2023
Composition of Vapor-Liquid-Solid III-V Ternary Nanowires Based on Group-III Intermix.
Article in Nanomaterials (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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3 citing papers in PubMed.
- Interplay of Kinetic and Thermodynamic Factors in the Stationary Composition of Vapor-Liquid-Solid IIIVNanomaterials (Basel, Switzerland) · 2024Article
- Circumventing the Uncertainties of the Liquid Phase in the Compositional Control of VLS III-V Ternary Nanowires Based on Group V Intermix.Nanomaterials (Basel, Switzerland) · 2024Article
- Composition of Vapor-Liquid-Solid III-V Ternary Nanowires Based on Group-III Intermix.Nanomaterials (Basel, Switzerland) · 2023Article
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Abstract
Compositional control in III-V ternary nanowires grown by the vapor-liquid-solid method is essential for bandgap engineering and the design of functional nanowire nano-heterostructures. Herein, we present rather general theoretical considerations and derive explicit forms of the stationary vapor-solid and liquid-solid distributions of vapor-liquid-solid III-V ternary nanowires based on group-III intermix. It is shown that the vapor-solid distribution of such nanowires is kinetically controlled, while the liquid-solid distribution is in equilibrium or nucleation-limited. For a more technologically important vapor-solid distribution connecting nanowire composition with vapor composition, the kinetic suppression of miscibility gaps at a growth temperature is possible, while miscibility gaps (and generally strong non-linearity of the compositional curves) always remain in the equilibrium liquid-solid distribution. We analyze the available experimental data on the compositions of the vapor-liquid-solid Al
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