Evidence map›Paper›PMID 37764242›Full record

ArticleMolecules (Basel, Switzerland)2023

Earth Abundant Oxidation Catalysts for Removal of Contaminants of Emerging Concern from Wastewater: Homogeneous Catalytic Screening of Monomeric Complexes.

Leslie Garcia, Makynna R Koper, Somrita Mondal, Joshua T Priddle, William A Truong, Elisabeth M A Allbritton, Ashtyn G McAdoo, Desiray J Cannon-Smith, Neil L Funwie, Tuyet Hoang and 6 more

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it
0cells of the map it votes in
0citing papers in PubMed
0.1field-weighted citation impact, top 61% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 1 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

16 authors at 4 institutions in 2 countries.

Leslie GarciaDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Makynna R KoperDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Somrita MondalDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Joshua T PriddleDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
William A TruongDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Elisabeth M A AllbrittonDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Ashtyn G McAdooDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Desiray J Cannon-SmithDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Neil L FunwieDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Tuyet HoangDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Inseo KimDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
David J HubinDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.
Jeanette A KrauseDepartment of Chemistry, University of Cincinnati, Cincinnati, OH 45220, USA.
Allen G OliverDepartment of Chemistry and Biochemistry, University of Notre Dame, Notre Dame, IN 46556, USA.ORCID 0000-0002-0511-1127
Timothy J PriorDepartment of Chemistry, School of Natural Sciences, University of Hull, Kingston Upon Hull HU6 7RX, UK.ORCID 0000-0002-7705-2701
Timothy J HubinDepartment of Chemistry and Physics, Southwestern Oklahoma State University, Weatherford, OK 73096, USA.ORCID 0000-0003-2277-1191
Southwestern Oklahoma State University · USUniversity of Cincinnati · USUniversity of Hull · GBUniversity of Notre Dame · US

Funding

American Chemical Society Petroleum Research Fund 60150-UR3National Science Foundation OIA-1946093
6 · The paper itself

Abstract

Twenty novel Mn, Fe, and Cu complexes of ethylene cross-bridged tetraazamacrocycles with potentially copolymerizable allyl and benzyl pendant arms were synthesized and characterized. Multiple X-ray crystal structures demonstrate the cis-folded pseudo-octahedral geometry forced by the rigidifying ethylene cross-bridge and show that two cis coordination cites are available for interaction with substrate and oxidant. The Cu complexes were used to determine kinetic stability under harsh acidic and high-temperature conditions, which revealed that the cyclam-based ligands provide superior stabilization with half-lives of many minutes or even hours in 5 M HCl at 50-90 °C. Cyclic voltammetry studies of the Fe and Mn complexes reveal reversible redox processes indicating stabilization of Fe

Indexed as

cross-bridged tetraazamacrocycledye bleachingoxidation catalyst

Identifiers

PMID37764242
PMCPMC10536317
OpenAlexW4386484263

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.