Evidence map›Paper›PMID 37764236›Full record

ArticleMolecules (Basel, Switzerland)2023

Oxidant-Free Electrochemical Direct Oxidative Benzyl Alcohols to Benzyl Aldehydes Using Three-Dimensional Printing PPAR Polyoxometalate.

Wenhui Zhang, Ran Liu, Xueyan Lv, Lirong Jiang, Silu Tang, Gang Liu, Guodong Shen, Xianqiang Huang, Chen Ma, Bingchuan Yang

Open access · goldAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.4field-weighted citation impact, top 49% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 4 citations in OpenAlex.

  1. Heterogeneous Indirect Redox Electrocatalysis in Electrolyte.Advanced materials (Deerfield Beach, Fla.) · 2026
    Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

10 authors at 2 institutions in 1 country.

Wenhui ZhangSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Ran LiuSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Xueyan LvSchool of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
Lirong JiangSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Silu TangSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Gang LiuSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Guodong ShenSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Xianqiang HuangSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Chen MaSchool of Chemistry and Chemical Engineering, Shandong University, Jinan 250100, China.
Bingchuan YangSchool of Chemistry and Chemical Engineering, Liaocheng University, Liaocheng 252000, China.
Liaocheng University · CNShandong University · CN

Funding

National Natural Science Foundation of China 21871125, 21802062, 21871026, 21401094Natural Science Foundation of Shandong Province ZR2019MB043, ZR2019QB022, ZR2017MB060
6 · The paper itself

Abstract

The oxidation of benzyl alcohols is an important reaction in organic synthesis. Traditional methods for benzyl alcohol oxidation have not been widely utilized due to the use of significant amounts of precious metals and environmentally unfriendly reagents. In recent years, electrocatalytic oxidation has gained significant attention, particularly electrochemical anodic oxidation, which offers a sustainable alternative for oxidation without the need for external oxidants or reducing agents. Here, a copper monosubstituted phosphotungstate-based polyacrylate resins (Cu-LPOMs@PPAR) catalyst has been fabricated with immobilization and recyclability using 3D printing technology that can be successfully applied in the electrocatalytic oxidation of benzyl alcohol to benzaldehyde, achieving atom economy and reducing pollution. In this protocol, we obtain benzaldehyde in good yields with excellent functional group toleration under metal-free and oxidant-free conditions. This strategy could provide a new avenue for heterogeneous catalysts in application for enhancing the efficiency and selectivity of electrocatalytic oxidation processes.

Indexed as

3D printingadditive manufacturingbenzaldehydebenzyl alcoholelectrocatalysispolyoxometalate

Identifiers

PMID37764236
PMCPMC10534777
OpenAlexW4386483823

What OpenQuestion holds

Textmetadata
LicenceCC BY
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.