ArticleAnalytical and bioanalytical chemistry2024
Determination of highly polar anionic pesticides in beehive products by hydrophilic interaction liquid chromatography coupled to mass spectrometry.
Article in Analytical and bioanalytical chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 6 papers.
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Who cites it
6 citing papers in PubMed, 15 citations in OpenAlex.
- [Determination of glufosinate and its metabolite residues in tea by ultra-high performance liquid chromatography-tandem mass spectrometry coupled with precolumn derivatization].Se pu = Chinese journal of chromatography · 2026Article
- Pesticide exposure risks and seasonal variation in honey bee-collected pollen across agricultural landscapes in Latvia.Environmental science and pollution research international · 2026Article
- The Development and Validation of an LC-MS/MS Method for the Determination of Glyphosate, AMPA, and Glufosinate in Honey Following FMOC-Cl Derivatization: Application to Italian Samples.Foods (Basel, Switzerland) · 2025Article
- Development and Validation of LC-MS/MS and IC-HRMS Methods for Highly Polar Pesticide Detection in Honeybees: A Multicenter Study for the Determination of Pesticides in Honeybees to Support Pollinators and Environmental Protection.Journal of xenobiotics · 2025Article
- The bacterial species' degradation activities at maximum threshold doses of glyphosate across different pH levels and temperature glyphosate biodegradation by soil bacteria at high doses under variable pH and temperature.Frontiers in microbiology · 2025Article
- Preliminary data on glyphosate, glufosinate, and metabolite contamination in Italian honey samples.Italian journal of food safety · 2024Article
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Authors and funding
5 authors at 2 institutions in 2 countries.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The analysis of highly polar pesticides is challenging due to their unique physicochemical properties, requiring specialized chromatographic techniques for their accurate and sensitive detection. Furthermore, the high level of co-extracted polar matrix components that can co-elute with the analytes can interfere with the analysis. Consequently, there is lack of pesticide monitoring data, as the European Food Safety Authority has pointed out. This article explores the overcoming of such difficulties in the analysis of these compounds. Analytical methodologies for the extraction, clean-up, and direct determination of 11 highly polar anionic pesticides, including glyphosate, glufosinate, ethephon, fosetyl-aluminium, and their related metabolites in complex food matrices such as honey and pollen by hydrophilic interaction liquid chromatography coupled to tandem mass spectrometry were successfully developed and validated. Solid-phase extraction and micro-solid-phase extraction employing strong anion exchange (SAX) cartridges were implemented for clean-up. The automation and miniaturization of SAX clean-up for these compounds were achieved for the first time. For method validation, SANTE/11312/2021 guideline was followed. Recoveries were between 70 and 120%, with RSDs below 20%. Limits of quantitation ranged from 0.005 to 0.020 mg kg
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