Evidence map›Paper›PMID 37749099›Full record

ArticleNature communications2023

Strong signature of electron-vibration coupling in molecules on Ag(111) triggered by tip-gated discharging.

Chao Li, Christoph Kaspar, Ping Zhou, Jung-Ching Liu, Outhmane Chahib, Thilo Glatzel, Robert Häner, Ulrich Aschauer, Silvio Decurtins, Shi-Xia Liu and 3 more

Abstract read
In one paragraph

Article in Nature communications, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 13 papers.

0numbers the graph read from it
0cells of the map it votes in
13citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

13 citing papers in PubMed.

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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

13 authors.

Chao LiDepartment of Physics, University of Basel, Klingelbergstrasse 82, 4056, Basel, Switzerland. chao.li@unibas.ch.ORCID http://orcid.org/0000-0003-2125-9989
Christoph KasparInstitute of Physics, University of Freiburg, Hermann-Herder-Strasse 3, 79104, Freiburg, Germany.
Ping ZhouDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012, Bern, Switzerland.
Jung-Ching LiuDepartment of Physics, University of Basel, Klingelbergstrasse 82, 4056, Basel, Switzerland.ORCID http://orcid.org/0000-0002-9472-3343
Outhmane ChahibDepartment of Physics, University of Basel, Klingelbergstrasse 82, 4056, Basel, Switzerland.
Thilo GlatzelDepartment of Physics, University of Basel, Klingelbergstrasse 82, 4056, Basel, Switzerland.ORCID http://orcid.org/0000-0002-3533-4217
Robert HänerDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012, Bern, Switzerland.
Ulrich AschauerDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012, Bern, Switzerland.ORCID http://orcid.org/0000-0002-1165-6377
Silvio DecurtinsDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012, Bern, Switzerland.
Shi-Xia LiuDepartment of Chemistry, Biochemistry and Pharmaceutical Sciences, University of Bern, Freiestrasse 3, 3012, Bern, Switzerland. shi-xia.liu@unibe.ch.ORCID http://orcid.org/0000-0001-6104-4320
Michael ThossInstitute of Physics, University of Freiburg, Hermann-Herder-Strasse 3, 79104, Freiburg, Germany.
Ernst MeyerDepartment of Physics, University of Basel, Klingelbergstrasse 82, 4056, Basel, Switzerland. ernst.meyer@unibas.ch.ORCID http://orcid.org/0000-0001-6385-3412
Rémy PawlakDepartment of Physics, University of Basel, Klingelbergstrasse 82, 4056, Basel, Switzerland. remy.pawlak@unibas.ch.ORCID http://orcid.org/0000-0001-8295-7241

Funding

Deutsche Forschungsgemeinschaft (German Research Foundation) INST 40/575-1 FUGGEC | EU Framework Programme for Research and Innovation H2020 | H2020 Priority Excellent Science | H2020 European Research Council (H2020 Excellent Science - European Research Council) 834402Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) 200020_188445Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) 200021_204053Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) 51NF40-180604Schweizerischer Nationalfonds zur Förderung der Wissenschaftlichen Forschung (Swiss National Science Foundation) PP00P2_187185
6 · The paper itself

Abstract

Electron-vibration coupling is of critical importance for the development of molecular electronics, spintronics, and quantum technologies, as it affects transport properties and spin dynamics. The control over charge-state transitions and subsequent molecular vibrations using scanning tunneling microscopy typically requires the use of a decoupling layer. Here we show the vibronic excitations of tetrabromotetraazapyrene (TBTAP) molecules directly adsorbed on Ag(111) into an orientational glassy phase. The electron-deficient TBTAP is singly-occupied by an electron donated from the substrate, resulting in a spin 1/2 state, which is confirmed by a Kondo resonance. The TBTAP

Identifiers

PMID37749099
PMCPMC10519934

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.