ArticleChemical science2023
Guest-induced pore breathing controls the spin state in a cyanido-bridged framework.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
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Who cites it
3 citing papers in PubMed.
- Quantitative Photoswitching of Spin States in o-Fluoroazobenzene-Loaded Metal-Organic Frameworks.Angewandte Chemie (International ed. in English) · 2026Article
- "Ammonia Induced Framework Transformations and Spin-Crossover in Fe(II) Hofmann MOFs".Inorganic chemistry · 2026Article
- Optical Phenomena in Molecule-Based Magnetic Materials.Chemical reviews · 2024Review
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Authors and funding
7 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Iron(ii) spin cross-over (SCO) compounds combine a thermally driven transition from the diamagnetic low-spin (LS) state to the paramagnetic high-spin (HS) state with a distinct change in the crystal lattice volume. Inversely, if the crystal lattice volume was modulated post-synthetically, the spin state of the compound could be tunable, resulting in the inverse effect for SCO. Herein, we demonstrate such a spin-state tuning in a breathing cyanido-bridged porous coordination polymer (PCP), where the volume change resulting from guest-induced gate-opening and -closing directly affects its spin state. We report the synthesis of a three-dimensional coordination framework {[Fe
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