ArticleChemical science2023
Synthesis and metalation of polycatechol nanohoops derived from fluorocycloparaphenylenes.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.
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Who cites it
8 citing papers in PubMed.
- Bridging [8]cyclo-Chemical science · 2026Article
- Article
- A dual-responsive cationic acridinium nanohoop: redox activity and acid/base-controlled reversible guest capture and release.Chemical science · 2026Article
- A Precisely Bromo-Functionalized [9]Cycloparaphenylene as a Platform for Late-Stage Multisite π-Extension Toward Chiral Nanohoops.Angewandte Chemie (International ed. in English) · 2026Article
- Macrocyclic geminal diols: synthesis, structures, stability and photophysical properties.Chemical science · 2026Article
- Synthesis and crystal structures of a family of bimetallic complexes with phenyl-substituted bridging tetraoxolene ligands.Acta crystallographica. Section C, Structural chemistry · 2025Article
- Thiophene-fused aromatic belts.Nature communications · 2025Article
- Diversification of Bipyridines and Azaheterocycles via Nucleophilic Displacement of Trimethylammoniums.ACS organic & inorganic Au · 2024Article
Corrections and comments
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Authors and funding
8 authors.
Funding
Abstract
Due to their unique topology and distinct physical properties, cycloparaphenylenes (CPPs) are attractive building blocks for new materials synthesis. While both noncovalent interactions and irreversible covalent bonds have been used to link CPP monomers into extended materials, a coordination chemistry approach remains less explored. Here we show that nucleophilic aromatic substitution reactions can be leveraged to rapidly introduce donor groups (-OR, -SR) onto polyfluorinated CPP rings. Demethylation of methoxide-substituted CPPs produces polycatechol nanohoop ligands that are readily metalated to produce well-defined, multimetallic CPP complexes. As catechols are recurring motifs throughout coordination chemistry and dynamic covalent chemistry, the polycatechol nanohoops reported here open the door to new strategies for the bottom-up synthesis of atomically precise CPP-based materials.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.