Evidence map›Paper›PMID 37728410›Full record

ArticleEnvironmental science. Processes & impacts2023

Limitations of conventional approaches to identify photochemically produced reactive intermediates involved in contaminant indirect photodegradation.

Reid P Milstead, Stephanie M Berg, Bella M Kelly, Christian D Knellwolf, Cooper J Larson, Kristine H Wammer, Christina K Remucal

Open access · greenAbstract read
PubMed Full text at PMC Publisher
In one paragraph

Article in Environmental science. Processes & impacts, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
0.3field-weighted citation impact, top 54% of its field
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed, 4 citations in OpenAlex.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors at 2 institutions in 1 country.

Reid P MilsteadEnvironmental Chemistry and Technology Program, University of Wisconsin-Madison, 660 N. Park St., Madison, Wisconsin 53706, USA. remucal@wisc.edu.
Stephanie M BergEnvironmental Chemistry and Technology Program, University of Wisconsin-Madison, 660 N. Park St., Madison, Wisconsin 53706, USA. remucal@wisc.edu.
Bella M KellyDepartment of Chemistry, University of St. Thomas, St. Paul, Minnesota 55105, USA.
Christian D KnellwolfDepartment of Chemistry, University of St. Thomas, St. Paul, Minnesota 55105, USA.
Cooper J LarsonDepartment of Chemistry, University of St. Thomas, St. Paul, Minnesota 55105, USA.
Kristine H WammerDepartment of Chemistry, University of St. Thomas, St. Paul, Minnesota 55105, USA.ORCID http://orcid.org/0000-0003-2067-892X
Christina K RemucalEnvironmental Chemistry and Technology Program, University of Wisconsin-Madison, 660 N. Park St., Madison, Wisconsin 53706, USA. remucal@wisc.edu.ORCID http://orcid.org/0000-0003-4285-7638
University of St. Thomas - Minnesota · USUniversity of Wisconsin–Madison · US

Funding

Ultra High Resolution Mass Spectrometer for Biomedical ResearchS10OD018475 · OD · UNIVERSITY OF WISCONSIN-MADISON · PI GE, YING · 2015 to 2015
$2.0M
NIH HHS S10 OD018475
6 · The paper itself

Abstract

Dissolved organic matter (DOM) mediated indirect photodegradation can play an important role in the degradation of aquatic contaminants. Predicting the rate of this process requires knowledge of the photochemically produced reactive intermediates (PPRI) that react with the compound of interest, as well as the ability of individual DOM samples to produce PPRI. Key PPRI are typically identified using quencher studies, yet this approach often leads to results that are difficult to interpret. In this work, we analyze the indirect photodegradation of atorvastatin, carbamazepine, sulfadiazine, and benzotriazole using a diverse set of 48 waters from natural and engineered aquatic systems. We use this large data set to evaluate relationships between PPRI formation and indirect photodegradation rate constants, which are directly compared to results using standard quenching experiments. These data demonstrate that triplet state DOM (

Indexed as

Water Pollutants, ChemicalAtorvastatinCarbamazepineDissolved Organic MatterPhotolysisSulfadiazineAtorvastatinCarbamazepineDissolved Organic MatterSulfadiazineWater Pollutants, Chemical

Identifiers

PMID37728410
PMCPMC10591881
OpenAlexW4386750536

What OpenQuestion holds

Textmetadata
LicenceTDM
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.