ArticleNature chemistry2024
Linkage conversions in single-crystalline covalent organic frameworks.
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Article in Nature chemistry, 2024. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 31 papers.
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31 citing papers in PubMed.
- π-Bridge Modulation in Three-Motif Covalent Organic Framework for Efficient HAngewandte Chemie (International ed. in English) · 2026Article
- Covalent Organic Framework Membranes through Sequential Imine Exchange for Precise Molecular Separation.Nano-micro letters · 2026Article
- Dimensional Isomerism in COFs Enabled by Spirobifluorene Substitution for Enhanced Photocatalytic COAngewandte Chemie (International ed. in English) · 2026Article
- Thermoresponsive and xenon-triggered gate-opening in flexible three-dimensional covalent organic framework for selective xenon capture.Nature communications · 2026Article
- Tridentate Coordination-Driven Covalent Organic Frameworks Incorporating Recycled Cobalt(II) for Enhanced Photocatalytic COSmall (Weinheim an der Bergstrasse, Germany) · 2026Article
- Superprotonic conductivity in crystalline and amorphous framework materials under anhydrous conditions.Chemical science · 2026Review
- Crystalline covalent organic polymer as an effective zincophilic protective layer to boost the performance of aqueous zinc-ion batteries.Chemical science · 2026Article
- Dynamic covalent organic frameworks.Chemical science · 2026Review
- Single-crystal 2D covalent organic frameworks for high-capacity methane storage.Nature communications · 2026Article
- Enhanced proton conductivity in azole-functionalized three-dimensional crystalline covalent organic frameworks.Nature communications · 2026Article
- Radial growth of twist-stacked covalent organic framework nanofibers.Nature communications · 2025Article
- Reversible transformation of single-crystal two-dimensional polymer framework for photo/thermal reversible photolithography.Chemical science · 2025Article
- Steric effect of intermediates induces formation of three-dimensional covalent organic frameworks.Nature communications · 2025Article
- Creating free standing covalent organic framework membranes by nanocrystal suturing in sol gel solutions.Nature communications · 2025Article
- Surfactant-Assisted Construction of Covalent Organic Frameworks.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2025Review
- Guest-induced structural transformation of single-crystal 3D covalent organic framework at room and high temperatures.Nature communications · 2025Article
- Synthesis of single-crystalline spNature chemistry · 2025Article
- 3D N-heterocyclic covalent organic frameworks for urea photosynthesis from NHNature communications · 2025Article
- 2.5-dimensional covalent organic frameworks.Nature communications · 2025Article
- Robust dioxin-linked metallophthalocyanine tbo topology covalent organic frameworks and their photocatalytic properties.National science review · 2025Article
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Authors and funding
17 authors.
Baoqiu Yu *Beijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, China.ORCID http://orcid.org/0000-0003-3379-7581
Rui-Biao Lin *MOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou, China.ORCID http://orcid.org/0000-0003-3267-220X
Gang XuState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China.ORCID http://orcid.org/0000-0001-8562-0724
Zhi-Hua FuState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China.
Hui WuCenter for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD, USA.ORCID http://orcid.org/0000-0003-0296-5204
Wei ZhouCenter for Neutron Research, National Institute of Standards and Technology, Gaithersburg, MD, USA.ORCID http://orcid.org/0000-0002-5461-3617
Shanfu LuBeijing Key Laboratory of Bio-Inspired Energy Materials and Devices, School of Space and Environment, Beihang University, Beijing, China.
Qian-Wen LiState Key Laboratory of Structural Chemistry, Fujian Provincial Key Laboratory of Materials and Techniques toward Hydrogen Energy, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, China.
Yucheng JinBeijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, China.ORCID http://orcid.org/0000-0002-7008-4938
Jing-Hong LiMOE Key Laboratory of Bioinorganic and Synthetic Chemistry, School of Chemistry, IGCME, Sun Yat-Sen University, Guangzhou, China.
Zhenguo ZhangBeijing Key Laboratory of Bio-Inspired Energy Materials and Devices, School of Space and Environment, Beihang University, Beijing, China.
Hailong WangBeijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, China. hlwang@ustb.edu.cn.ORCID http://orcid.org/0000-0002-0138-2966
Zier YanRigaku Beijing Corporation, Beijing, China.
Xiaolin LiuBeijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, China.
Kang WangBeijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, China.ORCID http://orcid.org/0000-0001-9405-5499
Banglin ChenFujian Provincial Key Laboratory of Polymer Materials, College of Chemistry and Materials Science, Fujian Normal University, Fuzhou, China. banglin.chen@fjnu.edu.cn.ORCID http://orcid.org/0000-0001-8707-8115
Jianzhuang JiangBeijing Advanced Innovation Center for Materials Genome Engineering, Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry and Chemical Engineering, School of Chemistry and Biological Engineering, University of Science and Technology Beijing, Beijing, China. jianzhuang@ustb.edu.cn.ORCID http://orcid.org/0000-0003-0454-9685
Funding
National Natural Science Foundation of China (National Science Foundation of China) 21631003National Natural Science Foundation of China (National Science Foundation of China) 22090061National Natural Science Foundation of China (National Science Foundation of China) 22101307National Natural Science Foundation of China (National Science Foundation of China) 22131005National Natural Science Foundation of China (National Science Foundation of China) 22171263National Natural Science Foundation of China (National Science Foundation of China) 22175020National Natural Science Foundation of China (National Science Foundation of China) 22178012National Natural Science Foundation of China (National Science Foundation of China) 22235001National Natural Science Foundation of China (National Science Foundation of China) 91961115
Abstract
Single-crystal X-ray diffraction is a powerful characterization technique that enables the determination of atomic arrangements in crystalline materials. Growing or retaining large single crystals amenable to it has, however, remained challenging with covalent organic frameworks (COFs), especially suffering from post-synthetic modifications. Here we show the synthesis of a flexible COF with interpenetrated qtz topology by polymerization of tetra(phenyl)bimesityl-based tetraaldehyde and tetraamine building blocks. The material is shown to be flexible through its large, anisotropic positive thermal expansion along the c axis (α
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