Evidence map›Paper›PMID 37719036›Full record

ArticleChemistry of materials : a publication of the American Chemical Society2023

Alignment of Breathing Metal-Organic Framework Particles for Enhanced Water-Driven Actuation.

Jacopo Andreo, Alejandra Durán Balsa, Min Ying Tsang, Anna Sinelshchikova, Orysia Zaremba, Stefan Wuttke, Jia Min Chin

Abstract read
In one paragraph

Article in Chemistry of materials : a publication of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Review
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

7 authors.

Jacopo AndreoBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, Leioa 48940, Spain.ORCID https://orcid.org/0000-0002-8153-5802
Alejandra Durán BalsaFaculty of Chemistry, Department of Functional Materials and Catalysis, University of Vienna, Währingerstr. 42, Vienna A-1090, Austria.ORCID https://orcid.org/0000-0003-1256-2767
Min Ying TsangFaculty of Chemistry, Department of Functional Materials and Catalysis, University of Vienna, Währingerstr. 42, Vienna A-1090, Austria.
Anna SinelshchikovaBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, Leioa 48940, Spain.
Orysia ZarembaBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, Leioa 48940, Spain.
Stefan WuttkeBCMaterials, Basque Center for Materials, Applications and Nanostructures, UPV/EHU Science Park, Leioa 48940, Spain.ORCID https://orcid.org/0000-0002-6344-5782
Jia Min ChinFaculty of Chemistry, Department of Functional Materials and Catalysis, University of Vienna, Währingerstr. 42, Vienna A-1090, Austria.ORCID https://orcid.org/0000-0002-0540-1597

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

As the majority of known metal-organic frameworks (MOFs) possess anisotropic crystal lattices and thus anisotropic physicochemical properties, a pressing practical challenge in MOF research is the establishment of robust and simple processing methods to fully harness the anisotropic properties of the MOFs in various applications. We address this challenge by applying an E-field to precisely align MIL-88A microcrystals and generate MIL-88A@polymer films. Thereafter, we demonstrate the impact of MOF crystal alignment on the actuation properties of the films as a proof of concept. We investigate how different anisotropies of the MIL-88A@polymer films, specifically, crystal anisotropy, particle alignment, and film composition, can lead to the synergetic enhancement of the film actuation upon water exposure. Moreover, we explore how the directionality in application of the external stimuli (dry/humid air stream, water/air interface) affects the direction and the extent of the MIL-88A@polymer film movement. Apart from the superior water-driven actuation properties of the developed films, we demonstrate by dynamometer measurements the higher degree of mechanical work performed by the aligned MIL-88A@polymer films with the preserved anisotropies compared to the unaligned films. The insights provided by this work into anisotropic properties displayed by aligned MIL-88A@polymer films promise to translate crystal performance benefits measured in laboratories into real-world applications. We anticipate that our work is a starting point to utilize the full potential of anisotropic properties of MOFs.

Identifiers

PMID37719036
PMCPMC10500993

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.