Amino-induced cadmium metal-organic framework based on thiazole ligand as a heterogeneous catalyst for the epoxidation of alkenes.

Fatemeh Moghadaskhou, Akram Karbalaee Hosseini, Azadeh Tadjarodi, Mehdi Abroudi

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Article in Scientific reports, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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4 authors.

Fatemeh MoghadaskhouResearch Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology (IUST), Tehran, 16846-13114, Iran.

Akram Karbalaee HosseiniResearch Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology (IUST), Tehran, 16846-13114, Iran.

Azadeh TadjarodiResearch Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology (IUST), Tehran, 16846-13114, Iran. tajarodi@iust.ac.ir.

Mehdi AbroudiResearch Laboratory of Inorganic Materials Synthesis, Department of Chemistry, Iran University of Science and Technology (IUST), Tehran, 16846-13114, Iran.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Selective epoxidation of olefins is of high interest in the chemical industry due to the many applications of epoxides. This study reports on the synthesis of Cd-MOF, [Cd(DPTTZ)(5-AIP)] (IUST-1) (where DPTTZ = 2, 5-di (pyridine-4-yl) thiazolo [5, 4-d] thiazole, 5-AIP = 5-Aminoisophthalic acid), by a reflux method, which can be considered as a fast and simple process. The morphology and structure of the synthesized IUST-1 were determined by using FE-SEM (Field Emission Scanning Electron Microscopy), EDX (Energy Dispersive Analysis of X-ray), Mapping (Elemental Mapping), CHNS (Elemental analysis), XRD (X-Ray Diffraction), FT-IR (Fourier Transform Infrared), and TGA (Thermo Gravimetric Analysis). The epoxidation of cyclooctene was investigated using the activity of catalytic IUST-1. The results showed that in the presence of tert-butyl hydroperoxide and CCl

Identifiers

PMID37717066

DOI10.1016/j.mcat.2019.110498

PMCPMC10505202

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.