ArticleJournal of the American Chemical Society2023
Furan Release via Force-Promoted Retro-[4+2][3+2] Cycloaddition.
Article in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 7 papers.
What it found
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Who cites it
7 citing papers in PubMed.
- Forces in mechanically interlocked materials.Chemical Society reviews · 2026Review
- Logic-Gated Release of a Dual Payload from a β-Lactam Mechanophore with a Rotaxane Actuator.Angewandte Chemie (International ed. in English) · 2025Article
- Selective Scission of Orthogonal Bonds in Four-Membered Ring Mechanophores upon Activation by a Rotaxane Actuator.Angewandte Chemie (International ed. in English) · 2025Article
- Advancing the Mechanosensitivity of Atropisomeric Diarylethene Mechanophores through a Lever-Arm Effect.Journal of the American Chemical Society · 2025Article
- Pushing vs Pulling: The Unique Geometry of Mechanophore Activation in a Rotaxane Force Actuator.Journal of the American Chemical Society · 2024Article
- Article
- Multimechanophore Polymers for Mechanically Triggered Small Molecule Release with Ultrahigh Payload Capacity.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Mechanophores (mechanosensitive molecules) have been instrumental in the development of various force-controlled release systems. However, the release of functional organic molecules is often the consequence of a secondary (nonmechanical) process triggered by an initial bond scission. Here we present a new mechanophore, built around an oxanorbornane-triazoline core, that is able to release a furan molecule following a force-promoted double retro-[4+2][3+2] cycloaddition. We explored this unprecedented transformation experimentally (sonication) and computationally (DFT, CoGEF) and found that the observed reactivity is controlled by the geometry of the adduct, as this reaction pathway is only accessible to the
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Registered trials
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