ArticleChemical science2023
2,3-Diarylmaleate salts as a versatile class of diarylethenes with a full spectrum of photoactivity in water.
Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.
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Who cites it
2 citing papers in PubMed.
- Towards Greener Synthesis of Substituted 3-Aminophthalates Starting from 2Molecules (Basel, Switzerland) · 2025Article
- Synthesis of Bis-Thioacid Derivatives of Diarylethene and Their Photochromic Properties.ACS omega · 2024Article
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Authors and funding
10 authors.
Funding
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Abstract
There is incessant interest in the transfer of common chemical processes from organic solvents to water, which is vital for the development of bioinspired and green chemical technologies. Diarylethenes feature a rich photochemistry, including both irreversible and reversible reactions that are in demand in organic synthesis, materials chemistry, and photopharmacology. Herein, we introduce the first versatile class of diarylethenes, namely, potassium 2,3-diarylmaleates (DAMs), that show excellent solubility in water. DAMs obtained from highly available precursors feature a full spectrum of photoactivity in water and undergo irreversible reactions (oxidative cyclization or rearrangement) or reversible photocyclization (switching), depending on their structure. This finding paves a way towards wider application of diarylethenes in photopharmacology and bioinspired technologies that require aqueous media for photochemical reactions.
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