Evidence map›Paper›PMID 37712032›Full record

ArticleChemical science2023

Dynamic self-assembly of supramolecular catalysts from precision macromolecules.

Qian Qin, Jie Li, David Dellemme, Mathieu Fossépré, Gabriella Barozzino-Consiglio, Imane Nekkaa, Adrian Boborodea, Antony E Fernandes, Karine Glinel, Mathieu Surin and 1 more

Abstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Qian QinInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.
Jie LiInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.
David DellemmeLaboratory for Chemistry of Novel Materials, Université de Mons - UMONS Avenue Maistriau, 17 B-7000 Mons Belgium mathieu.surin@umons.ac.be.
Mathieu FossépréLaboratory for Chemistry of Novel Materials, Université de Mons - UMONS Avenue Maistriau, 17 B-7000 Mons Belgium mathieu.surin@umons.ac.be.
Gabriella Barozzino-ConsiglioInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.
Imane NekkaaInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.
Adrian BoborodeaCertech rue Jules Bordet 45 7180 Seneffe Belgium.
Antony E FernandesInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.
Karine GlinelInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.ORCID https://orcid.org/0000-0002-2000-0169
Mathieu SurinLaboratory for Chemistry of Novel Materials, Université de Mons - UMONS Avenue Maistriau, 17 B-7000 Mons Belgium mathieu.surin@umons.ac.be.ORCID https://orcid.org/0000-0001-8950-3437
Alain M JonasInstitute of Condensed Matter and Nanosciences, Université catholique de Louvain Croix du Sud 1 L7.04.02, Louvain-la-Neuve Belgium alain.jonas@uclouvain.be.ORCID https://orcid.org/0000-0002-4083-0688

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We show the emergence of strong catalytic activity at low concentrations in dynamic libraries of complementary sequence-defined oligomeric chains comprising pendant functional catalytic groups and terminal recognition units. In solution, the dynamic constitutional library created from pairs of such complementary oligomers comprises free oligomers, self-assembled di(oligomeric) macrocycles, and a virtually infinite collection of linear poly(oligomeric) chains. We demonstrate, on an exemplary catalytic system requiring the cooperation of no less than five chemical groups, that supramolecular di(oligomeric) macrocycles exhibit a catalytic turnover frequency

Identifiers

PMID37712032
PMCPMC10498719

What OpenQuestion holds

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LicenceCC BY-NC
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.