ArticleACS applied polymer materials2023
Development and Digital Light Processing 3D Printing of a Vitrimer Composed of Glycerol 1,3-Diglycerolate Diacrylate and Tetrahydrofurfuryl Methacrylate.
Article in ACS applied polymer materials, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 5 papers.
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Who cites it
5 citing papers in PubMed.
- Diblock Copolymer Engineered Swim Bladder Membrane Enables Spatiotemporal Synchronized Defense and Pro-Healing in Challenging Soft Tissue Regeneration.Advanced materials (Deerfield Beach, Fla.) · 2026Article
- Development of biobased dynamic thiol-acrylate photopolymers: 3D-printed self-healing and shape memory materials.RSC advances · 2025Article
- Antimicrobial Vitrimers Synthesized from Dipentaerythritol Pentaacrylate and 2-Hydroxy-3-phenoxypropyl Acrylate for LCD 3D Printing.Biomacromolecules · 2025Article
- Non-Isocyanate Urethane Acrylate Derived from Isophorone Diamine: Synthesis, Characterization and Its Application in 3D Printing.Molecules (Basel, Switzerland) · 2024Article
- Thermo-Responsive Shape-Memory Dual-Cured Polymers Based on Vegetable Oils.Materials (Basel, Switzerland) · 2023Article
Corrections and comments
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Authors and funding
4 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
The development of biobased reshapable and repairable vitrimers has received extensive attention due to the growing focus on an environmentally friendly society. Therefore, the objective of this research was to synthesize sustainable polymers with an environmentally friendly strategy combining the benefits of renewable resources, UV curing, and vitrimers. Two biobased monomers, glycerol 1,3-diglycerolate diacrylate and tetrahydrofurfuryl methacrylate, were chosen for the preparation of UV-curable resins and tested by real-time photorheometry and RT-FTIR spectroscopy to determine their suitability for digital light processing (DLP) 3D printing. DLP 3D-printed polymer showed shape memory, weldability, and repairability capabilities by triggering the dynamic transesterification process at high temperatures. The vitrimer with a weight ratio of 60:40 of glycerol 1,3-diglycerolate diacrylate and tetrahydrofurfuryl methacrylate showed shape memory properties with a recovery ratio of 100% and a 7-fold improved tensile strength compared to the original sample, confirming efficient weldability and repairability.
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Registered trials
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