ArticleRSC advances2023
Evaluation of the catalytic activity of Zn-MOF-74 for the alcoholysis of cyclohexene oxide.
J Gabriel Flores, Juan L Obeso, V Martínez-Jiménez, Nancy Martín-Guaregua, Alejandro Islas-Jácome, Eduardo González-Zamora, Héctor Serrano-Espejel, Britney Mondragón-Rodríguez, Carolina Leyva, D A Solís-Casados and 4 more
Abstract read
In one paragraphArticle in RSC advances, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.
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14 authors.
J Gabriel FloresDepartamento de Ingeniería de Procesos e Hidráulica, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico jarh@xanum.uam.mx.
Juan L ObesoInstituto Politécnico Nacional, CICATA U. Legaria, Laboratorio Nacional de Ciencia, Tecnología y Gestión Integrada del Agua (LNAgua) Legaria 694 Irrigación, Miguel Hidalgo CDMX Mexico.ORCID https://orcid.org/0000-0002-8876-9484 V Martínez-JiménezDepartamento de Ingeniería de Procesos e Hidráulica, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico jarh@xanum.uam.mx.
Nancy Martín-GuareguaDepartamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico rperalta@izt.uam.mx.
Alejandro Islas-JácomeDepartamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico rperalta@izt.uam.mx.
Eduardo González-ZamoraDepartamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico rperalta@izt.uam.mx.ORCID https://orcid.org/0000-0002-3995-9126 Héctor Serrano-EspejelDepartamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico rperalta@izt.uam.mx.
Britney Mondragón-RodríguezDepartamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico rperalta@izt.uam.mx.
Carolina LeyvaInstituto Politécnico Nacional, CICATA U. Legaria, Laboratorio Nacional de Ciencia, Tecnología y Gestión Integrada del Agua (LNAgua) Legaria 694 Irrigación, Miguel Hidalgo CDMX Mexico.ORCID https://orcid.org/0000-0003-4327-9569 D A Solís-CasadosCentro Conjunto de Investigación en Química Sustentable UAEM-UNAM Carretera Toluca-Atlacomulco Km 14.5, Unidad San Cayetano Toluca 50200 Estado de México Mexico.
Ilich A IbarraLaboratorio de Fisicoquímica y Reactividad de Superficies (LaFReS) Instituto de Investigaciones en Materiales, Universidad Nacional Autónoma de México Circuito Exterior s/n, CU Coyoacán 04510, Ciudad de México Mexico.ORCID https://orcid.org/0000-0002-8573-8033 Ricardo A PeraltaDepartamento de Química, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico rperalta@izt.uam.mx.ORCID https://orcid.org/0000-0001-7573-2968 Julia Aguilar-PliegoÁrea de Química Aplicada, Departamento de Ciencias Básicas, Universidad Autónoma Metropolitana-Azc Apotzalco 02200 Ciudad de México Mexico apj@azc.uam.mx.
José Antonio de Los ReyesDepartamento de Ingeniería de Procesos e Hidráulica, División de Ciencias Básicas e Ingeniería, Universidad Autónoma Metropolitana-Iztapalapa 09340 Ciudad de México Mexico jarh@xanum.uam.mx.
Funding
No grant is acknowledged in the PubMed record.
6 · The paper itselfAbstract
In the present work, nanocrystalline Zn-MOF-74 is shown to be a heterogeneous catalyst for the acid-catalyzed ring-opening alcoholysis of cyclohexene oxide. The results corroborated that accessible open metal sites within the material are critical conditions (Zn(ii) Lewis acid sites) for this reaction. Zn-MOF-74 was tested at three different temperatures (30, 40, and 50 °C) for the alcoholysis reaction. Furthermore, the cyclohexene oxide conversion was 94% in less than two days. A comparison of the catalytic activity with different crystal sizes of Zn-MOF-74 and the homogenous phase, zinc acetate, was conducted. Zn-MOF-74 exhibited excellent catalytic cyclability for three cycles without losing its activity. The material showed chemical stability by retaining its crystalline structure after the reaction and cyclability process.
Identifiers
PMID37701278
PMCPMC10493851
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LicenceCC BY-NC
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