Evidence map›Paper›PMID 37691462›Full record

ArticlePhilosophical transactions. Series A, Mathematical, physical, and engineering sciences2023

The local ordering of polar solvents around crystalline carbon nitride nanosheets in solution.

Martin C Wilding, Chris Benmore, Thomas F Headen, Camilla Di Mino, Thomas S Miller, Theo M Suter, Furio Corà, Adam J Clancy, Andrea Sella, Paul McMillan and 1 more

Abstract read
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In one paragraph

Article in Philosophical transactions. Series A, Mathematical, physical, and engineering sciences, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 1 paper.

0numbers the graph read from it
0cells of the map it votes in
1citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

1 citing paper in PubMed.

  1. Exploring the length scales, timescales and chemistry of challenging materials (Part 2).Philosophical transactions. Series A, Mathematical, physical, and engineering sciences · 2023
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Martin C WildingUK Catalysis Hub, Research Complex at Harwell, Rutherford Appleton Laboratory, Oxfordshire OX11 0QX, UK.ORCID 0000-0002-0802-0423
Chris BenmoreX-Ray Science Division, Advanced Photon Source, Argonne National Laboratory, Argonne, IL, USA.ORCID 0000-0001-7007-7749
Thomas F HeadenISIS Neutron and Muon Source, Science and Technology Facilities Council, Rutherford Appleton Laboratory, Oxfordshire OX11 0QX, UK.ORCID 0000-0003-0095-5731
Camilla Di MinoDepartment of Physics and Astronomy, University College London, London WC1E 6BT, UK.ORCID 0000-0002-3211-2678
Thomas S MillerElectrochemical Innovation Laboratory, Department of Chemical Engineering, University College London, London WC1E 7JE, UK.
Theo M SuterElectrochemical Innovation Laboratory, Department of Chemical Engineering, University College London, London WC1E 7JE, UK.
Furio CoràDepartment of Chemistry, University College London, London WC1E 6BT, UK.
Adam J ClancyDepartment of Chemistry, University College London, London WC1E 6BT, UK.ORCID 0000-0002-1791-8999
Andrea SellaDepartment of Chemistry, University College London, London WC1E 6BT, UK.
Paul McMillanDepartment of Chemistry, University College London, London WC1E 6BT, UK.ORCID 0000-0002-5298-780X
Christopher A HowardDepartment of Physics and Astronomy, University College London, London WC1E 6BT, UK.

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The crystalline graphitic carbon nitride, poly-triazine imide (PTI) is highly unusual among layered materials since it is spontaneously soluble in aprotic, polar solvents including dimethylformamide (DMF). The PTI material consists of layers of carbon nitride intercalated with LiBr. When dissolved, the resulting solutions consist of dissolved, luminescent single to multilayer nanosheets of around 60-125 nm in diameter and Li+ and Br- ions originating from the intercalating salt. To understand this unique solubility, the structure of these solutions has been investigated by high-energy X-ray and neutron diffraction. Although the diffraction patterns are dominated by inter-solvent correlations there are clear differences between the X-ray diffraction data of the PTI solution and the solvent in the 4-6 Å

Indexed as

carbon nitridehigh-energy X-ray diffractionliquid structureneutron diffractionsolvent ordering

Identifiers

PMID37691462
PMCPMC10493548

What OpenQuestion holds

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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.