Nickel-Imidazolium Low Transition Temperature Mixtures with Lewis-Acidic Character.

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Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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1 · What the graph read from it

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0 citing papers in PubMed.

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4 · The record

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5 · Who and what money

Authors and funding

2 authors.

Mario MartosInstitute of Organic Synthesis, University of Alicante, ctra. San Vicente del Raspeig s/n, San Vicente del Raspeig, 03690 Alicante, Spain.ORCID 0000-0001-7057-9618

Isidro M PastorInstitute of Organic Synthesis, University of Alicante, ctra. San Vicente del Raspeig s/n, San Vicente del Raspeig, 03690 Alicante, Spain.ORCID 0000-0002-8271-0641

Funding

Generalitat Valenciana AICO/2021/013Generalitat Valenciana IDIFEDER/2021/013Ministerio de Ciencia e Innovación PID2021-127332NB-I00University of Alicante UADIF22-04University of Alicante UAUSTI22-23University of Alicante VIGROB-316

6 · The paper itself

Abstract

Low transition temperature mixtures (LTTMs) are a new generation of solvents that have found extensive application in organic synthesis. The interactions between the components often generate highly activated, catalytically active species, thus opening the possibility of using LTTMs as catalysts, rather than solvents. In this work, we introduce a nickel-based imidazolium LTTM, study its thermal behavior and explore its catalytic activity in the solvent-free allylation of heterocycles with allylic alcohols. This system is effective in this reaction, affording the corresponding products in excellent yield without the need for additional purifications, thus resulting in a very environmentally friendly protocol.

Indexed as

allylic alcoholsimidazolium saltslow transition temperature mixturessustainable chemistrytetrachloronickelates

Identifiers

PMID37687182

DOI10.3390/molecules28176338

PMCPMC10490159

What OpenQuestion holds

Textmetadata

LicenceCC BY

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.