Coordinatively Unsaturated Nickel Nitroxyl Complex: Structure, Physicochemical Properties, and Reactivity toward Dioxygen.

Kiyoshi Fujisawa, Taisei Kataoka, Kohei Terashima, Haruka Kurihara, Felipe de Santis Gonçalves, Nicolai Lehnert

Open access · goldAbstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it

0cells of the map it votes in

2citing papers in PubMed

0.4field-weighted citation impact, top 45% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed, 4 citations in OpenAlex.

Reductive and Oxidative Transformations of Nitrite at Nickel(II): Insights into the Generation, Electronic Structure, and Reactivity of {NiNO}JACS Au · 2026
Article
Exploring the chemical and biological landscape of a Nickel (II) schiff base complex via azomethine linkage.Scientific reports · 2025
Article

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

6 authors at 2 institutions in 2 countries.

Kiyoshi FujisawaDepartment of Chemistry, Ibaraki University, Mito 310-8512, Ibaraki, Japan.ORCID 0000-0002-4023-0025

Taisei KataokaDepartment of Chemistry, Ibaraki University, Mito 310-8512, Ibaraki, Japan.

Kohei TerashimaDepartment of Chemistry, Ibaraki University, Mito 310-8512, Ibaraki, Japan.

Haruka KuriharaDepartment of Chemistry, Ibaraki University, Mito 310-8512, Ibaraki, Japan.

Felipe de Santis GonçalvesDepartment of Chemistry and Department of Biophysics, University of Michigan, 930 N. University Avenue, Ann Arbor, MI 48109, USA.

Nicolai LehnertDepartment of Chemistry and Department of Biophysics, University of Michigan, 930 N. University Avenue, Ann Arbor, MI 48109, USA.ORCID 0000-0002-5221-5498

Ibaraki University · JPUniversity of Michigan · US

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

For its important roles in biology, nitrogen monoxide (·NO) has become one of the most studied and fascinating molecules in chemistry. ·NO itself acts as a "noninnocent" or "redox active" ligand to transition metal ions to give metal-NO (M-NO) complexes. Because of this uncertainty due to redox chemistry, the real description of the electronic structure of the M-NO unit requires extensive spectroscopic and theoretical studies. We previously reported the Ni-NO complex with a hindered N3 type ligand [Ni(NO)(L3)] (L3

Indexed as

crystal structureN2 ligandnickelnitrosylnoninnocent ligandoxidation reaction

Identifiers

PMID37687034

DOI10.3390/molecules28176206

PMCPMC10489029

OpenAlexW4386098499

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.