ArticleInorganic chemistry2023
Linker-Functionalized Phosphinate Metal-Organic Frameworks: Adsorbents for the Removal of Emerging Pollutants.
Article in Inorganic chemistry, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.
What it found
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Who cites it
3 citing papers in PubMed.
- Toward Scalability: Fe-MOF-Based Ultrafiltration Membrane for Effective Microplastics Removal from Drinking Water at Point-of-Use.Global challenges (Hoboken, NJ) · 2026Article
- Magnetism, Mössbauer Spectroscopy, and Proton Conductivity of Coordination Polymers Based on Phosphonate and Phosphinate Linkers.The journal of physical chemistry. C, Nanomaterials and interfaces · 2025Article
- Linker-Functionalized Phosphinate Metal-Organic Frameworks: Adsorbents for the Removal of Emerging Pollutants.Inorganic chemistry · 2023Article
Corrections and comments
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Authors and funding
9 authors.
Funding
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Abstract
Metal-organic frameworks (MOFs) are attracting increasing attention as adsorbents of contaminants of emerging concern that are difficult to remove by conventional processes. This paper examines how functional groups covering the pore walls of phosphinate-based MOFs affect the adsorption of specific pharmaceutical pollutants (diclofenac, cephalexin, and sulfamethoxazole) and their hydrolytic stability. New structures, isoreticular to the phosphinate MOF ICR-7, are presented. The phenyl ring facing the pore wall of the presented MOFs is modified with dimethylamino groups (ICR-8) and ethyl carboxylate groups (ICR-14). These functionalized MOFs were obtained from two newly synthesized phosphinate linkers containing the respective functional groups. The presence of additional functional groups resulted in higher affinity toward the tested pollutants compared to ICR-7 or activated carbon. However, this modification also comes with a reduced adsorption capacity. Importantly, the introduction of the functional groups enhanced the hydrolytic stability of the MOFs.
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Registered trials
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