ArticleScience (New York, N.Y.)2023
Oxidative addition of an alkyl halide to form a stable Cu(III) product.
Article in Science (New York, N.Y.), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 25 papers.
What it found
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The trial behind it
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Who cites it
25 citing papers in PubMed.
- Enantioselective Access to Trifluoromethylated Spirocyclopropyl Heterocycles.Advanced science (Weinheim, Baden-Wurttemberg, Germany) · 2026Article
- Lewis acidity of a high-valent copper(iii) acetylacetonate.RSC advances · 2026Article
- Repurposing trifluoromethyl copper (III) complexes for difluoromethylation of saccharides and complex alcohols.Nature communications · 2026Article
- Article
- Copper-Catalyzed Three-Component Selective 1,4-Amino Oxygenation of 1,3-Dienes.Angewandte Chemie (International ed. in English) · 2026Article
- Harnessing COJournal of the American Chemical Society · 2026Article
- A reflection on recent advances in organometallic copper(iii) chemistry.Chemical science · 2026Article
- Trifluoromethylation of alkyl electrophiles withScience (New York, N.Y.) · 2025Article
- Light-driven radical copper-catalyzed allylic amination via allylic copper intermediates.Nature communications · 2025Article
- Article
- Copper(II)-Photocatalyzed Radical Anellation of Nitroalkanes with Alkenes or Alkynes for the Synthesis of Isoxazolines and Isoxazoles.Angewandte Chemie (International ed. in English) · 2025Article
- Platform Design Enabling Silver(III) Stabilization ─ The Uprise of AgChemistry (Weinheim an der Bergstrasse, Germany) · 2025Review
- Synthesis of chiral difluoromethyl cyclopropanes through desymmetric difluoromethylation of cyclopropenes enabled by enantioselective copper catalysis.Nature synthesis · 2025Article
- Mechanistic insights into nonlinear effects in copper-catalyzed asymmetric esterification.Nature communications · 2025Article
- Enantioconvergent copper-catalysed difluoromethylation of alkyl halides.Nature catalysis · 2024Article
- Three Distinct Oxidation States (II/II, II/III, and III/III) of Diorganocopper Complexes.JACS Au · 2024Article
- Overcoming Copper Reduction Limitation in Asymmetric Substitution: Aryl-Radical-Enabled Enantioconvergent Cyanation of Alkyl Iodides.Journal of the American Chemical Society · 2024Article
- Directed copper-catalyzed C-H functionalization of unactivated olefins with azodicarbonamide compounds.RSC advances · 2024Article
- Synthesis and application of well-defined [PhChemical science · 2024Article
- CuH-Catalyzed Regio- and Enantioselective Formal Hydroformylation of Vinyl Arenes.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
6 authors.
Funding
Abstract
The step that cleaves the carbon-halogen bond in copper-catalyzed cross-coupling reactions remains ill defined because of the multiple redox manifolds available to copper and the instability of the high-valent copper product formed. We report the oxidative addition of α-haloacetonitrile to ionic and neutral copper(I) complexes to form previously elusive but here fully characterized copper(III) complexes. The stability of these complexes stems from the strong Cu-CF
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.