ReviewJournal of the American Chemical Society2023
Frustrated Radical Pairs in Organic Synthesis.
Review in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 17 papers.
What it found
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The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.
The trial behind it
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Who cites it
17 citing papers in PubMed.
- Molecular orbital node engineering in pyrene: linking chemical reactivity with room-temperature phosphorescence.National science review · 2026Article
- Flavin Hydroperoxide and Semiquinone: Structures and Biomimetic Activity.Journal of the American Chemical Society · 2026Article
- Post-polymerisation modification of polyolefins through C-H bond activation by frustrated radical pairs.Chemical communications (Cambridge, England) · 2026Article
- Rotational observation of kinetically hindered neutral radical pairs.Nature communications · 2026Article
- Review
- Article
- Thiol-Free Sulfenylation Redefined: A Single-Atom Transfer Pathway to Symmetrical Di(hetero)arylthioethers via B(CJournal of the American Chemical Society · 2026Article
- Harnessing redox properties of organic persistent radicals in SET-induced transformations.Beilstein journal of organic chemistry · 2026Review
- Nitrogen-Centered Organic Persistent Radicals Catalyze Redox-Neutral C─C Bond Forming Reactions.Angewandte Chemie (International ed. in English) · 2025Article
- Radical Formation by Direct Single Electron Transfer between Nitrobenzene and Anionic Organo Bases.ACS omega · 2025Article
- Hexaphenyl-1,2-Diphosphonium Dication [PhJournal of the American Chemical Society · 2025Article
- B(CChemistry (Weinheim an der Bergstrasse, Germany) · 2025Article
- Synthesis and Photochemical Uncaging of Alkene-Protected, Polymer-Bound Vicinal Frustrated Lewis Pairs.Journal of the American Chemical Society · 2024Article
- Mechanistic studies on single-electron transfer in frustrated Lewis pairs and its application to main-group chemistry.Chemical Society reviews · 2024Review
- Sequential radical and cationic reactivity at separated sites within one molecule in solution.Chemical science · 2024Article
- Coordination-induced O-H/N-H bond weakening by a redox non-innocent, aluminum-containing radical.Nature communications · 2024Article
- Light-Induced Polymeric Frustrated Radical Pairs as Building Blocks for Materials and Photocatalysts.Journal of the American Chemical Society · 2023Article
Corrections and comments
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Authors and funding
5 authors.
Funding
Abstract
Frustrated radical pairs (FRPs) describe the phenomenon that two distinct radicals─which would otherwise annihilate each other to form a closed-shell covalent adduct─can coexist in solution, owing to steric repulsion or weak bonding association. FRPs are typically formed via spontaneous single-electron transfer between two sterically encumbered precursors─an oxidant and a reductant─under ambient conditions. The two components of a FRP exhibit orthogonal chemical properties and can often act in cooperativity to achieve interesting radical reactivities. Initially observed in the study of traditional frustrated Lewis pairs, FRPs have recently been shown to be capable of homolytically activating various chemical bonds. In this Perspective, we will discuss the discovery of FRPs, their fundamental reactivity in chemical bond activation, and recent developments of their use in synthetic organic chemistry, including in C-H bond functionalization. We anticipate that FRPs will provide new reaction strategies for solving challenging problems in modern organic synthesis.
Identifiers
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.