Evidence map›Paper›PMID 37655015›Full record

ArticleChemical science2023

The Marcus dimension: identifying the nuclear coordinate for electron transfer from

Adam Šrut, Benjamin J Lear, Vera Krewald

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In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 3 papers.

0numbers the graph read from it
0cells of the map it votes in
3citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

3 citing papers in PubMed.

  1. Mapping Proton-Coupled Electron Transfer With Real Space Coordinates.Angewandte Chemie (International ed. in English) · 2026
    Article
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4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Adam ŠrutDepartment of Chemistry, Theoretical Chemistry, TU Darmstadt Peter-Grünberg-Straße 4 64287 Darmstadt Germany vera.krewald@tu-darmstadt.de.ORCID https://orcid.org/0000-0002-4486-1940
Benjamin J LearDepartment of Chemistry, The Pennsylvania State University University Park PA 16802 USA bul14@psu.edu.
Vera KrewaldDepartment of Chemistry, Theoretical Chemistry, TU Darmstadt Peter-Grünberg-Straße 4 64287 Darmstadt Germany vera.krewald@tu-darmstadt.de.ORCID https://orcid.org/0000-0002-4749-4357

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The Marcus model forms the foundation for all modern discussion of electron transfer (ET). In this model, ET results in a change in diabatic potential energy surfaces, separated along an ET nuclear coordinate. This coordinate accounts for all nuclear motion that promotes electron transfer. It is usually assumed to be dominated by a collective asymmetric vibrational motion of the redox sites involved in the ET. However, this coordinate is rarely quantitatively specified. Instead, it remains a nebulous concept, rather than a tool for gaining true insight into the ET pathway. Herein, we describe an

Identifiers

PMID37655015
PMCPMC10466304

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.