Evidence map›Paper›PMID 37654574›Full record

ArticleJACS Au2023

Structure-Property Relationships for Nickel Aluminate Catalysts in Polyethylene Hydrogenolysis with Low Methane Selectivity.

Brandon C Vance, Sean Najmi, Pavel A Kots, Cong Wang, Sungho Jeon, Eric A Stach, Dmitri N Zakharov, Nebojsa Marinkovic, Steven N Ehrlich, Lu Ma and 1 more

Abstract read
In one paragraph

Article in JACS Au, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 11 papers.

0numbers the graph read from it
0cells of the map it votes in
11citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

11 citing papers in PubMed.

  1. Article
  2. Article
  3. Article
  4. Article
  5. Synergy Effects in a Bimetallic Ru ─ Pt Alloy Catalyst for Low-HChemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  6. Article
  7. Review
  8. Article
  9. Catalytic Upcycling of Polyolefins.Chemical reviews · 2024
    Review
  10. Article
  11. Review
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

11 authors.

Brandon C VanceCenter for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States.
Sean NajmiCenter for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States.
Pavel A KotsCenter for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States.ORCID https://orcid.org/0000-0003-3582-4600
Cong WangCenter for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States.ORCID https://orcid.org/0000-0002-0451-344X
Sungho JeonDepartment of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.
Eric A StachDepartment of Materials Science and Engineering, University of Pennsylvania, Philadelphia, Pennsylvania 19104, United States.ORCID https://orcid.org/0000-0002-3366-2153
Dmitri N ZakharovCenter for Functional Nanomaterials, Brookhaven National Laboratory, 735 Brookhaven Avenue, Upton, New York 11973, United States.
Nebojsa MarinkovicDepartment of Chemical Engineering, Columbia University, 500W 120th Street, New York, New York 10027, United States.
Steven N EhrlichNational Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973, United States.
Lu MaNational Synchrotron Light Source, Brookhaven National Laboratory, Upton, New York 11973, United States.
Dionisios G VlachosCenter for Plastics Innovation, University of Delaware, 221 Academy Street, Newark, Delaware 19716, United States.ORCID https://orcid.org/0000-0002-6795-8403

Funding

Pilot Research Subproject ProgramP30GM110758 · NIGMS · UNIVERSITY OF DELAWARE · PI BEEBE, THOMAS PAUL · 2014 to 2018
$5.8M
NIGMS NIH HHS P30 GM110758
6 · The paper itself

Abstract

Earth-abundant metals have recently been demonstrated as cheap catalyst alternatives to scarce noble metals for polyethylene hydrogenolysis. However, high methane selectivities hinder industrial feasibility. Herein, we demonstrate that low-temperature ex-situ reduction (350 °C) of coprecipitated nickel aluminate catalysts yields a methane selectivity of <5% at moderate polymer deconstruction (25-45%). A reduction temperature up to 550 °C increases the methane selectivity nearly sevenfold. Catalyst characterization (XRD, XAS,

Identifiers

PMID37654574
PMCPMC10466342

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC-ND
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.