ReviewJournal of the American Chemical Society2023
Binding, Sensing, And Transporting Anions with Pnictogen Bonds: The Case of Organoantimony Lewis Acids.
Review in Journal of the American Chemical Society, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 21 papers.
What it found
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Who cites it
21 citing papers in PubMed.
- Short Sb···Sb Contacts in Polymorphic Tris(p-Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid-State Chemistry?Angewandte Chemie (International ed. in English) · 2026Article
- σ-Hole Engineering Enables Selective Supramolecular Isomer Formation in Sb(III) Hosts.Inorganic chemistry · 2026Article
- Flash Communication: Intramolecular Chalcogen Bonding as a Driver of Diaryltelluride Oxidation byOrganometallics · 2026Article
- Fluoride ions as charge carriers in electrochemical energy storage.Nature materials · 2026Review
- Bridging Lewis acidic antimony centers with electron-withdrawing carborane cages.Chemical science · 2026Article
- Structurally Constrained Stibenium: Metallomimetic C-Si Bond Activation.Angewandte Chemie (International ed. in English) · 2026Article
- Pnictogen-bonding-crosslinked polymer networks: constructing self-healing materials.Chemical science · 2026Article
- Molecular Electrostatic Surface Potential: A Predictive Framework for Noncovalent Interactions and Adsorption Characteristics in Molecular Entities.International journal of molecular sciences · 2026Review
- Design Rules for Sb and Bi Porphyrin Capsules: Para-Substitution Effects and Pnictogen Bond Conformational Control.Inorganic chemistry · 2026Article
- Flash Communication: Properties and Applications of a Pentavalent Bromoantimony Lewis Acid.Organometallics · 2026Article
- Air-Stable Cobalt-Semiquinone Radical Complexes on Carbon Nanotubes: A Redox Switch for Anion Response.Journal of the American Chemical Society · 2025Article
- Pnictogen-Bonding Catalysis: Copolymerization of COACS catalysis · 2025Article
- Interplay Between Stereochemically Active Lone Pair Repulsions, Sigma Hole Interactions, and Delocalized Redox Processes in Topochemical Fluoride-Ion Insertion.Angewandte Chemie (International ed. in English) · 2025Article
- Lewis Acidity of the SbClAngewandte Chemie (International ed. in English) · 2025Article
- Applications of Antimony in Catalysis.ACS organic & inorganic Au · 2025Review
- Steric Selection of Anion Binding Sites by Organoantimony(V) Pnictogen Bond Donors: An Experimental and Computational Study.Inorganic chemistry · 2024Article
- Pnictogen Bonding at the Core of a Carbene-Stiborane-Gold Complex: Impact on Structure and Reactivity.Organometallics · 2024Article
- A Sterically Accessible Monomeric Stibine Oxide Activates Organotetrel(IV) Halides, Including C-F and Si-F Bonds.Journal of the American Chemical Society · 2024Article
- Exploring the Effects of Se Basicity on a Te···Se Interaction Supported by a Rigid Indazolium Backbone.Organometallics · 2024Article
- Tunable Pnictogen Bonding at the Service of Hydroxide Transport across Phospholipid Bilayers.Journal of the American Chemical Society · 2024Article
Corrections and comments
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Authors and funding
2 authors.
Funding
No grant is acknowledged in the PubMed record.
Abstract
Motivated by the discovery of main group Lewis acids that could compete or possibly outperform the ubiquitous organoboranes, several groups, including ours, have engaged in the chemistry of Lewis acidic organoantimony compounds as new platforms for anion capture, sensing, and transport. Principal to this approach are the intrinsically elevated Lewis acidic properties of antimony, which greatly favor the addition of halide anions to this group 15 element. The introduction of organic substituents to the antimony center and its oxidation from the + III to the + V state provide for tunable Lewis acidity and a breadth of applications in supramolecular chemistry and catalysis. The performances of these antimony-based Lewis acids in the domain of anion sensing in aqueous media illustrate the favorable attributes of antimony as a central element. At the same time, recent advances in anion binding catalysis and anion transport across phospholipid membranes speak to the numerous opportunities that lie ahead in the chemistry of these unique main group compounds.
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Registered trials
Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.