Evidence map›Paper›PMID 37638542›Full record

ArticleACS macro letters2023

Topological Entanglement of Linear Catenanes: Knots and Threadings.

Zahra Ahmadian Dehaghani, Pietro Chiarantoni, Cristian Micheletti

Abstract read
In one paragraph

Article in ACS macro letters, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 2 papers.

0numbers the graph read from it
0cells of the map it votes in
2citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

2 citing papers in PubMed.

  1. Article
  2. Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

3 authors.

Zahra Ahmadian DehaghaniInternational School for Advanced Studies (SISSA), Via Bonomea 265, 34136 Trieste, Italy.
Pietro ChiarantoniInternational School for Advanced Studies (SISSA), Via Bonomea 265, 34136 Trieste, Italy.ORCID 0000-0002-9249-863X
Cristian MichelettiInternational School for Advanced Studies (SISSA), Via Bonomea 265, 34136 Trieste, Italy.ORCID 0000-0002-1022-1638

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

We used molecular dynamics simulations to investigate the self-entanglements of the collapsed linear catenanes. We found two different types of topologically complex states. First, we observed numerous long-lived knotting events of the catenane backbone. However, comparison with conventional polymers reveals that knots are suppressed in catenanes. Next, we observed topologically complex states with no analogue in polymers, where a concatenated ring was threaded by other near or distal rings sliding through it. Differently from knots, these threaded states can disentangle by becoming fully tightened. A detailed thermodynamic and microscopic analysis is employed to rationalize the persistence of threaded states, which can survive significant internal reorganizations of the entire catenane. We finally discuss the broader implications of these previously unreported types of entanglements for other systems, such as noncollapsed and interacting catenanes.

Identifiers

PMID37638542
PMCPMC10515615

What OpenQuestion holds

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LicenceCC BY
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Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.