Impact of Static-Oriented Electric Fields on the Kinetics of Some Representative Suzuki-Miyaura and Metal-Cluster Mediated Reactions.

Navya Arepalli, Sukanta Mondal, Debdutta Chakraborty, Pratim Kumar Chattaraj

Open access · goldAbstract read

In one paragraph

Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

–field-weighted citation impact, top 95% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 0 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 1 country.

Navya ArepalliDepartment of Chemistry, Birla Institute of Technology, Mesra, Ranchi 835215, Jharkhand, India.ORCID 0009-0007-3820-1843

Sukanta MondalDepartment of Education, A. M. School of Educational Sciences, Assam University, Silchar 788011, Assam, India.ORCID 0000-0003-1918-8202

Debdutta ChakrabortyDepartment of Chemistry, Birla Institute of Technology, Mesra, Ranchi 835215, Jharkhand, India.ORCID 0000-0002-2569-1990

Pratim Kumar ChattarajDepartment of Chemistry, Birla Institute of Technology, Mesra, Ranchi 835215, Jharkhand, India.ORCID 0000-0002-5650-7666

Birla Institute of Technology, Mesra · INAssam University · IN

Funding

DST J .C. Bose FellowshipScience and Engineering Research Board SRG/2022/001280

6 · The paper itself

Abstract

In order to examine the effect of oriented (static) electric fields (OEF) on the kinetics of some representative Suzuki-Miyaura and metal-cluster mediated reactions at ambient temperatures, density functional theory-based calculations are reported herein. Results indicate that, in general, OEF can facilitate the kinetics of the concerned reactions when applied along the suitable direction (parallel or anti-parallel with respect to the reaction axis). The reverse effect happens if the direction of the OEF is flipped. OEF (when applied along the 'right' direction) helps to polarize the transition states in the desired direction, thereby facilitating favorable bonding interactions. Given the growing need for finding appropriate catalysts among the scientific community, OEF can prove to be a vital route for the same.

Indexed as

kineticsmetal clusteroriented electric fieldSuzuki–Miyaura reactiontransition state stabilization

Identifiers

PMID37630421

DOI10.3390/molecules28166169

PMCPMC10459314

OpenAlexW4386027158

What OpenQuestion holds

Textmetadata

LicenceCC BY

Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.