Trivinylphosphine Oxide: Synthesis, Characterization, and Polymerization Reactivity Investigated Using Single-Crystal Analysis and Density Functional Theory.

Khalifah A Salmeia, Akef T Afaneh, Reem R Habash, Antonia Neels

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Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

0numbers the graph read from it

0cells of the map it votes in

0citing papers in PubMed

0.1field-weighted citation impact, top 54% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

0 citing papers in PubMed, 1 citations in OpenAlex.

No citing paper in PubMed yet.

4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

4 authors at 2 institutions in 2 countries.

Khalifah A SalmeiaDepartment of Chemistry, Faculty of Science, Al-Balqa Applied University, Al-Salt 19117, Jordan.ORCID 0000-0003-2541-9652

Akef T AfanehDepartment of Chemistry, Faculty of Science, Al-Balqa Applied University, Al-Salt 19117, Jordan.ORCID 0000-0001-8353-9578

Reem R HabashDepartment of Chemistry, Faculty of Science, Al-Balqa Applied University, Al-Salt 19117, Jordan.

Antonia NeelsCenter for X-ray Analytics, Swiss Federal Laboratories for Materials Science and Technology (Empa), 8600 Dübendorf, Switzerland.ORCID 0000-0001-5752-2852

Al-Balqa Applied University · JOSwiss Federal Laboratories for Materials Science and Technology · CH

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

Organophosphorus chemicals are versatile and important in industry. Trivinylphosphine oxide (TVPO), for example, exhibited a promising precursor as a flame-retardant additive for industrial applications. Density functional theory (DFT) simulations were used to explore the kinetic and thermodynamic chemical processes underlying the nucleophilic addition reactions of TVPO in order to better understand their polymerization mechanisms. An experimental X-ray single-crystal study of TVPO supported this work's theory based on its computed findings. TVPO was prepared using POCl

Indexed as

DFT calculationsGrignard reagentkinetic and thermodynamic comparisonMichael-like additionorganophosphorusreaction profileX-ray analysis

Identifiers

PMID37630349

DOI10.3390/molecules28166097

PMCPMC10459575

OpenAlexW4385949317

What OpenQuestion holds

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LicenceCC BY

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Registered trials

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.