A Chiral Relay Race: Stereoselective Synthesis of Axially Chiral Biaryl Diketones through Ring-Opening of Optical Dihydrophenan-threne-9,10-diols.

Lei Shi, Jiawei Zhu, Biqiong Hong, Zhenhua Gu

Open access · goldAbstract read

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Article in Molecules (Basel, Switzerland), 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Not yet cited in PubMed.

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0citing papers in PubMed

0.1field-weighted citation impact, top 55% of its field

1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

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0 citing papers in PubMed, 1 citations in OpenAlex.

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4 · The record

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5 · Who and what money

Authors and funding

4 authors at 2 institutions in 1 country.

Lei ShiHefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei 230026, China.

Jiawei ZhuHefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei 230026, China.

Biqiong HongCollege of Materials and Chemical Engineering, Minjiang University, Fuzhou 350108, China.

Zhenhua GuHefei National Research Center for Physical Sciences at the Microscale, Department of Chemistry, University of Science and Technology of China, 96 Jinzhai Road, Hefei 230026, China.ORCID 0000-0001-8168-2012

University of Science and Technology of China · CNMinjiang University · CN

Funding

Foundation of Fujian Education Department JAT220323Minjiang University MJY20019, MYK21007National Natural Science Foundation of China 92056102Natural Science Foundation of Fujian Province 2023J011395

6 · The paper itself

Abstract

We report herein a point-to-axial chirality transfer reaction of optical dihydrophenanthrene-9,10-diols for the synthesis of axially chiral diketones. Two sets of conditions, namely a basic

Indexed as

axially chiral diketoneC-C bond cleavagechiral relay racediol

Identifiers

PMID37630207

DOI10.3390/molecules28165956

PMCPMC10459955

OpenAlexW4385666309

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Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.