Evidence map›Paper›PMID 37621437›Full record

ArticleChemical science2023

Planar pentacoordinate s-block metals.

Meng-Hui Wang, Amlan J Kalita, Mesías Orozco-Ic, Gai-Ru Yan, Chen Chen, Bing Yan, Gabriela Castillo-Toraya, William Tiznado, Ankur K Guha, Sudip Pan and 2 more

Abstract read
In one paragraph

Article in Chemical science, 2023. The graph could read no effect estimate from its abstract, so it casts no vote on the map. Cited by 8 papers.

0numbers the graph read from it
0cells of the map it votes in
8citing papers in PubMed
–field-weighted citation impact
1 · What the graph read from it

What it found

Each row is one number read from the abstract, on the scale the paper reported it, with its interval. Left of the dashed line favours the treatment, right favours the comparator. Under each row is the sentence it came from. New to these charts? A ten-minute tutorial.

The abstract states no effect estimate the extractor could read, or names no intervention and outcome on the map, so this paper lights no cell and moves no belief. It is still indexed, cited and linked below.

2 · The registry

The trial behind it

Trials whose registry record cites this paper, or whose number appears in the abstract. A trial that started after this paper was published is citing it as background, not reporting it.

Neither the registry nor the abstract names a trial number. If this is a trial report, that itself is worth knowing.

3 · Its place in the literature

Who cites it

8 citing papers in PubMed.

  1. Planar Heptacoordinate Halogens.ACS physical chemistry Au · 2026
    Article
  2. Planar hexacoordinate chlorine.Chemical science · 2026
    Article
  3. Planar and Pyramidal Pentacoordinate Selenium Atoms.Chemistry (Weinheim an der Bergstrasse, Germany) · 2025
    Article
  4. Article
  5. Article
  6. FLiMolecules (Basel, Switzerland) · 2024
    Article
  7. Article
  8. Cl©LiMolecules (Basel, Switzerland) · 2024
    Article
4 · The record

Corrections and comments

PubMed lists nothing against this paper. Absence here is not a guarantee, only a check that was made.

5 · Who and what money

Authors and funding

12 authors.

Meng-Hui WangInstitute of Atomic and Molecular Physics, Jilin University Changchun 130023 China zcui@jlu.edu.cn sudip@jlu.edu.cn.
Amlan J KalitaAdvanced Computational Chemistry Centre, Department of Chemistry, Cotton University Panbazar Guwahati Assam 781001 India ankurkantiguha@gmail.com.ORCID https://orcid.org/0000-0001-8206-0071
Mesías Orozco-IcDonostia International Physics Center (DIPC) 20018 Donostia Euskadi Spain.ORCID https://orcid.org/0000-0001-7579-0607
Gai-Ru YanInstitute of Atomic and Molecular Physics, Jilin University Changchun 130023 China zcui@jlu.edu.cn sudip@jlu.edu.cn.
Chen ChenInstitute of Atomic and Molecular Physics, Jilin University Changchun 130023 China zcui@jlu.edu.cn sudip@jlu.edu.cn.
Bing YanInstitute of Atomic and Molecular Physics, Jilin University Changchun 130023 China zcui@jlu.edu.cn sudip@jlu.edu.cn.ORCID https://orcid.org/0000-0003-0641-3087
Gabriela Castillo-TorayaDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados Unidad Mérida. Km 6 Antigua Carretera a Progreso. Apdo. Postal 73, Cordemex 97310 Mérida Yucatan Mexico gmerino@cinvestav.mx.
William TiznadoCentro de Química Teórica & Computacional (CQT&C), Departamento de Ciencias Químicas, Facultad de Ciencias Exactas, Universidad Andres Bello Avenida República 275 Santiago Chile wtiznado@unab.cl.ORCID https://orcid.org/0000-0002-6061-8879
Ankur K GuhaAdvanced Computational Chemistry Centre, Department of Chemistry, Cotton University Panbazar Guwahati Assam 781001 India ankurkantiguha@gmail.com.ORCID https://orcid.org/0000-0003-4370-8108
Sudip PanInstitute of Atomic and Molecular Physics, Jilin University Changchun 130023 China zcui@jlu.edu.cn sudip@jlu.edu.cn.ORCID https://orcid.org/0000-0003-3172-926X
Gabriel MerinoDepartamento de Física Aplicada, Centro de Investigación y de Estudios Avanzados Unidad Mérida. Km 6 Antigua Carretera a Progreso. Apdo. Postal 73, Cordemex 97310 Mérida Yucatan Mexico gmerino@cinvestav.mx.ORCID https://orcid.org/0000-0002-2507-4052
Zhong-Hua CuiInstitute of Atomic and Molecular Physics, Jilin University Changchun 130023 China zcui@jlu.edu.cn sudip@jlu.edu.cn.ORCID https://orcid.org/0000-0002-0710-1774

Funding

No grant is acknowledged in the PubMed record.

6 · The paper itself

Abstract

The presence of a delocalized π-bond is often considered an essential criterion for achieving planar hypercoordination. Herein, we show that σ-delocalization could be sufficient to make the planar configuration the most stable isomer in a series of planar pentacoordinate s-block metals. High-level

Identifiers

PMID37621437
PMCPMC10445469

What OpenQuestion holds

Textmetadata
LicenceCC BY-NC
Read underepoch 390

Registered trials

None linked

Read under generation 80e0d062 · epoch 390. Bibliography from PubMed, PubMed Central and OpenAlex; grants from NIH RePORTER; trial links from ClinicalTrials.gov; estimates, votes and beliefs from the OpenQuestion graph.