Advances in the synthesis and applications of 2D MXene-metal nanomaterials.

MXenes, two-dimensional (2D) materials that consist of transition metal carbides, nitrides and/or carbonitrides, have recently attracted much attention in energy-related and biomedicine fields. These materials have substantial advantages over traditional carbon graphenes: they possess high conductivity, high strength, excellent chemical and mechanical stability, and superior hydrophilic properties. Furthermore, diverse functional groups such as -OH, -O, and -F located on the surface of MXenes aid the immobilization of numerous noble metal nanoparticles (NP). Therefore, 2D MXene composite materials have become an important and convenient option of being applied as support materials in many fields. In this review, the advances in the synthesis (including morphology studies, characterization, physicochemical properties) and applications of the currently known 2D MXene-metal (Pd, Ag, Au, and Cu) nanomaterials are summarized based on critical analysis of the literature in this field. Importantly, the current state of the art, challenges, and the potential for future research on broad applications of MXene-metal nanomaterials have been discussed.