Elastocapillary rolling transfer weaves soft materials to spatial structures.

Spatial structures of soft materials have attracted great attention because of emerging applications in wearable electronics, biomedical devices, and soft robotics, but there are no facile technologies available to assemble the soft materials into spatial structures. Here, we report a mechanical transfer route enabled by the rotational motion of curved substrates relative to the soft materials on liquid surface. This transfer can weave soft materials into a broad variety of spatial structures with controllable global weaving chirality and orders and could also produce local ear-like folds with programmable numbers and distributions. We further prove that multiple pieces of soft materials in different forms including wire, ribbon, and large-area film can be woven onto curved substrates with various three-dimensional geometry shapes. Application demonstrations on the woven freestanding spatial structures with on-demand weaving patterns and orders have been conducted to show the temperature-driven multimodal actuating functionalities for programmable robotic postures.